Strong hyperconjugative interactions limit solvent and substituent influence on conformational equilibrium: the case of <i>cis</i>-2-halocyclohexylamines.

Francisco, Camila B; Fernandes, Cleverton S; de Melo, Ulisses Z; Rittner, Roberto; Gauze, Gisele F; Basso, Ernani A

Strong hyperconjugative interactions limit solvent and substituent influence on conformational equilibrium: the case of cis-2-halocyclohexylamines.

Francisco, Camila B; Fernandes, Cleverton S; de Melo, Ulisses Z; Rittner, Roberto; Gauze, Gisele F; Basso, Ernani A.

Afiliação

Francisco CB; Chemistry Department, State University of Maringá, 5790, Maringá 87020-900, Brazil.
Fernandes CS; Chemistry Department, State University of Maringá, 5790, Maringá 87020-900, Brazil.
de Melo UZ; Chemistry Department, State University of Maringá, 5790, Maringá 87020-900, Brazil.
Rittner R; Chemistry Institute, University of Campinas, 6154, Campinas 13083-970, Brazil.
Gauze GF; Chemistry Department, State University of Maringá, 5790, Maringá 87020-900, Brazil.
Basso EA; Chemistry Department, State University of Maringá, 5790, Maringá 87020-900, Brazil.

Beilstein J Org Chem ; 15: 818-829, 2019.

Article em En | MEDLINE | ID: mdl-31019574

Palavras-chave

conformational equilibrium; cyclohexane derivatives; dynamic NMR; hyperconjugation; principal component analysis

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Beilstein J Org Chem Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Brasil

Texto completo

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PubMed Links

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Beilstein J Org Chem Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Brasil