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Visible-light-induced deboronative alkylarylation of acrylamides with organoboronic acids.
Li, Xuezhi; Han, Man-Yi; Wang, Bin; Wang, Lei; Wang, Min.
Afiliação
  • Li X; Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China. hanmy10@126.com wangmin204@chnu.edu.cn.
  • Han MY; Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China. hanmy10@126.com wangmin204@chnu.edu.cn.
  • Wang B; Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China. hanmy10@126.com wangmin204@chnu.edu.cn.
  • Wang L; Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China. hanmy10@126.com wangmin204@chnu.edu.cn and State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P R China.
  • Wang M; Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P.R. China. hanmy10@126.com wangmin204@chnu.edu.cn.
Org Biomol Chem ; 17(27): 6612-6619, 2019 07 21.
Article em En | MEDLINE | ID: mdl-31231744
ABSTRACT
A visible-light-induced deboronative alkylarylation of acrylamides with organoboronic acids was developed. In this transformation, boronic acids could be activated by the organic photocatalyst of eosin Y, generating alky free radicals in high efficiency. A broad range of substrate scope was examined and a number of 3,3-disubstituted oxindoles were synthesized in high yields.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2019 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2019 Tipo de documento: Article