Bioretention cell incorporating Fe-biochar and saturated zones for enhanced stormwater runoff treatment.

ABSTRACT

Nitrogen (N) and phosphorus (P) removal in conventional bioretention systems is highly variable. Therefore, five novel experimental columns with different media configurations and constituents, and incorporating a saturated zone were developed and assessed to optimize the removal of N, P and other nutrients. Three types of media composed of the conventional mixed sand and soil media (T1), biochar-amended media (T2), and iron-coated biochar (ICB)-amended media (T3) were evaluated. Two of the experimental columns were designed with double-layer configurations, while the other three were of a single-layer structure. Removal efficiencies of nutrients in the experimental columns were evaluated and compared using simulated runoff. Also, the effect of media depth on the retention of P and denitrifying enzyme activity (DEA) in the bioretention columns were evaluated. The experimental column only filled with T3 showed the best performance for COD, ammonia (NH4+-N) and total phosphorus (TP) removal (94.6%, 98.3% and 93.70%, respectively), whereas columns filled with T2 performed poorly for TP removal (57.36%). For the removal of nitrate (NO3--N) and total nitrogen (TN), the columns using a single-layer and only filled with either T3 or T2 exhibited the best performance (93% and 97% TN removal, respectively). Overall, this study demonstrates that our proposed single-layered bioretention cell only filled with T3 and incorporating a saturated zone effectively improves the runoff quality, and can provide a new bioretention cell configuration for efficient stormwater treatment.