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Inorganic-organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water.
Li, Zhong; Zhang, Jing; Lin, Li-Dan; Liu, Jin-Hua; Li, Xin-Xiong; Zheng, Shou-Tian.
Afiliação
  • Li Z; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China. lxx@fzu.edu.cn stzheng@fzu.edu.cn.
  • Zhang J; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China. lxx@fzu.edu.cn stzheng@fzu.edu.cn.
  • Lin LD; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China. lxx@fzu.edu.cn stzheng@fzu.edu.cn.
  • Liu JH; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China. lxx@fzu.edu.cn stzheng@fzu.edu.cn.
  • Li XX; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China. lxx@fzu.edu.cn stzheng@fzu.edu.cn.
  • Zheng ST; State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China. lxx@fzu.edu.cn stzheng@fzu.edu.cn.
Chem Commun (Camb) ; 55(78): 11735-11738, 2019 Sep 26.
Article em En | MEDLINE | ID: mdl-31512686
ABSTRACT
The first two inorganic-organic hybrid three-dimensional (3D) polyoxotantalates (POTas) and the first two inorganic-organic hybrid 2D POTas have been obtained. All of these high-dimensional POTas are built from a new-type POTa dimeric cluster {Cu(en)(Ta6O19)}2/{Cu(enMe)(Ta6O19)}2 (en = ethylenediamine, enMe = 1,2-diaminopropane) bridged by copper complexes. Interestingly, extended POTas 1 and 3 can undergo single-crystal to single-crystal structural transformations triggered by water.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2019 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2019 Tipo de documento: Article