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Luminescence-Driven Electronic Structure Determination in a Textbook Dimeric DyIII -Based Single-Molecule Magnet.
Guettas, Djamila; Gendron, Frédéric; Fernandez Garcia, Guglielmo; Riobé, François; Roisnel, Thierry; Maury, Olivier; Pilet, Guillaume; Cador, Olivier; Le Guennic, Boris.
Afiliação
  • Guettas D; Laboratoire des Multimatériaux et Interfaces (LMI), UMR 5615 CNRS, Université Claude Bernard Lyon 1, bâtiment Chevreul, Avenue du 11 novembre 1918, 69622, Villeurbanne cedex, France.
  • Gendron F; CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, Univ Rennes 1, 35000, Rennes, France.
  • Fernandez Garcia G; CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, Univ Rennes 1, 35000, Rennes, France.
  • Riobé F; Dipartimento di Chimica "U.Schiff" and UdR INSTM, Università degli Studi di Firenze, Via della Lastruccia 3-13, 50019, Sesto Fiorentino, Italy.
  • Roisnel T; Univ Lyon, Ens de Lyon, CNRS UMR 5182, Université Claude Bernard Lyon 1, Laboratoire de Chimie, F69342, Lyon, France.
  • Maury O; CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, Univ Rennes 1, 35000, Rennes, France.
  • Pilet G; Univ Lyon, Ens de Lyon, CNRS UMR 5182, Université Claude Bernard Lyon 1, Laboratoire de Chimie, F69342, Lyon, France.
  • Cador O; Laboratoire des Multimatériaux et Interfaces (LMI), UMR 5615 CNRS, Université Claude Bernard Lyon 1, bâtiment Chevreul, Avenue du 11 novembre 1918, 69622, Villeurbanne cedex, France.
  • Le Guennic B; CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, Univ Rennes 1, 35000, Rennes, France.
Chemistry ; 26(19): 4389-4395, 2020 Apr 01.
Article em En | MEDLINE | ID: mdl-31943417
A textbook dysprosium dinuclear complex based on acetylacetone ligands, [Dy2 (acac)4 (µ2 -acac)2 (H2 O)2 ], has been synthesized and fully characterized. This simple dimeric lanthanide complex shows well-resolved solid-state luminescence and behaves as a single-molecule magnet under zero DC field. A seminal crystal-field approach is used to marry both magnetism and luminescence in the frame of an energetic picture.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article País de afiliação: França
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article País de afiliação: França