All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters.
Chem Commun (Camb)
; 56(71): 10305-10308, 2020 Sep 14.
Article
em En
| MEDLINE
| ID: mdl-32756680
ABSTRACT
A series of POM-based all-inorganic open frameworks, H9[Ln9W8(µ4-O)12(µ2-O)24(H2O)24](SiW12O40)3·60H2O (1-Ln, Ln = La, Pr and Nd), have been fabricated and structurally characterized for the first time. The unique architectures are constructed from nanoscale four-shell Ln@W8@Ln8@(SiW12)6 clusters. Additionally, the porous nature of the frameworks has also been investigated.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2020
Tipo de documento:
Article