Your browser doesn't support javascript.
loading
Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis.
Morvan, Jennifer; Vermersch, François; Zhang, Ziyun; Falivene, Laura; Vives, Thomas; Dorcet, Vincent; Roisnel, Thierry; Crévisy, Christophe; Cavallo, Luigi; Vanthuyne, Nicolas; Bertrand, Guy; Jazzar, Rodolphe; Mauduit, Marc.
Afiliação
  • Morvan J; Université de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, F-35000Rennes, France.
  • Vermersch F; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, United States.
  • Zhang Z; King Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC), Thuwal 23955-6900, Saudi Arabia.
  • Falivene L; Dipartimento di Chimica e Biologia, Università di Salerno, Via Papa Paolo Giovanni II, 84100 Fisiciano, Italy.
  • Vives T; Université de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, F-35000Rennes, France.
  • Dorcet V; Université de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, F-35000Rennes, France.
  • Roisnel T; Université de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, F-35000Rennes, France.
  • Crévisy C; Université de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, F-35000Rennes, France.
  • Cavallo L; King Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC), Thuwal 23955-6900, Saudi Arabia.
  • Vanthuyne N; Aix Marseille Université, CNRS, Centrale Marseille, iSm2, Marseille 13397, France.
  • Bertrand G; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, United States.
  • Jazzar R; UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, United States.
  • Mauduit M; Université de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, F-35000Rennes, France.
J Am Chem Soc ; 142(47): 19895-19901, 2020 11 25.
Article em En | MEDLINE | ID: mdl-33185429
ABSTRACT
An expedient access to the first optically pure ruthenium complexes containing C1-symmetric cyclic (alkyl)(amino)carbene ligands is reported. They demonstrate excellent catalytic performances in asymmetric olefin metathesis with high enantioselectivities (up to 92% ee). Preliminary mechanistic insights provided by density functional theory models highlight the origin of the enantioselectivity.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2020 Tipo de documento: Article País de afiliação: França
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2020 Tipo de documento: Article País de afiliação: França