Synthetic Enzyme-Catalyzed CO2 Fixation Reactions.
ChemSusChem
; 14(8): 1781-1804, 2021 Apr 22.
Article
em En
| MEDLINE
| ID: mdl-33631048
ABSTRACT
In recent years, (de)carboxylases that catalyze reversible (de)carboxylation have been targeted for application as carboxylation catalysts. This has led to the development of proof-of-concept (bio)synthetic CO2 fixation routes for chemical production. However, further progress towards industrial application has been hampered by the thermodynamic constraint that accompanies fixing CO2 to organic molecules. In this Review, biocatalytic carboxylation methods are discussed with emphases on the diverse strategies devised to alleviate the inherent thermodynamic constraints and their application in synthetic CO2 -fixation cascades.
Palavras-chave
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Dióxido de Carbono
/
Carboxiliases
Idioma:
En
Revista:
ChemSusChem
Assunto da revista:
QUIMICA
/
TOXICOLOGIA
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Reino Unido