Spontaneous nucleation on flat surface by depletion force in colloidal suspension.
Sci Rep
; 11(1): 8929, 2021 Apr 26.
Article
em En
| MEDLINE
| ID: mdl-33903604
ABSTRACT
Nucleation by sedimentation of colloidal particles on a flat surface is experimentally observed, and effect of attractive depletion force generated by polymers on nucleation is investigated. Sedimentation forms polycrystalline colloidal crystal on a flat surface, and above the threshold polymer concentration, ratio of the spontaneous nucleation increases, resulting in a decrease in the grain size, whereas dependence of the contact angle on the polymer concentration was not observed. We show that the interaction between particles and the flat surface mainly affects the spontaneous nucleation, not the interaction between the particles, and it is demonstrated that the nucleation process can be numerically reproduced using the rate equations.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Sci Rep
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Japão