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Facile C-N bond cleavage of primary aliphatic amines by (salen)ruthenium(VI) nitrido complexes.
Pan, Yunling; Cheng, Lin; Pan, Yi; Man, Wai-Lun; Yiu, Shek-Man; Xie, Jianhui; Lau, Kai-Chung; Lau, Tai-Chu.
Afiliação
  • Pan Y; School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, People's Republic of China. jianhuixie@hfut.edu.cn.
  • Cheng L; Department of Chemistry, City University of Hong Kong, Kowloon Tong, Hong Kong, P R China. bhtclau@cityu.edu.hk.
  • Pan Y; Department of Chemistry, City University of Hong Kong, Kowloon Tong, Hong Kong, P R China. bhtclau@cityu.edu.hk.
  • Man WL; Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong 999077, People's Republic of China.
  • Yiu SM; Department of Chemistry, City University of Hong Kong, Kowloon Tong, Hong Kong, P R China. bhtclau@cityu.edu.hk.
  • Xie J; School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, People's Republic of China. jianhuixie@hfut.edu.cn.
  • Lau KC; Department of Chemistry, City University of Hong Kong, Kowloon Tong, Hong Kong, P R China. bhtclau@cityu.edu.hk.
  • Lau TC; Department of Chemistry, City University of Hong Kong, Kowloon Tong, Hong Kong, P R China. bhtclau@cityu.edu.hk.
Dalton Trans ; 51(14): 5404-5408, 2022 Apr 05.
Article em En | MEDLINE | ID: mdl-35315483
We report the first example of oxidative cleavage of the strong C-N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C-N cleavage reaction comes from the formation of stable NN after the initial coupling of the amine N and the nitrido ligand.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article