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Total synthesis of (±)-mersicarpine following a 6-exo-trig radical cyclization.
Peng, Wan-Ling; Jhang, Yin-Jia; Chang, Chieh-Yu; Peng, Po-Kai; Zhao, Wei-Ting; Wu, Yen-Ku.
Afiliação
  • Peng WL; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan. yenkuwu@nycu.edu.tw.
  • Jhang YJ; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan. yenkuwu@nycu.edu.tw.
  • Chang CY; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan. yenkuwu@nycu.edu.tw.
  • Peng PK; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan. yenkuwu@nycu.edu.tw.
  • Zhao WT; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan. yenkuwu@nycu.edu.tw.
  • Wu YK; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan. yenkuwu@nycu.edu.tw.
Org Biomol Chem ; 20(31): 6193-6195, 2022 08 10.
Article em En | MEDLINE | ID: mdl-35467680
Described is a total synthesis of racemic mersicarpine from diethyl 4-oxopimelate. The synthetic route takes advantage of a 2-indolyl radical cyclization to construct the pyrido[1,2-a]indole scaffold bearing the all-carbon quaternary stereocenter.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Alcaloides Indólicos Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Taiwan
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Alcaloides Indólicos Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Taiwan