Your browser doesn't support javascript.
loading
Stereocontrolled Pericyclic and Radical Cycloaddition Reactions of Readily Accessible Chiral Alkenyl Diazaborolidines.
Zhang, Mingkai; Xu, Peilin; Vendola, Alex J; Allais, Christophe; Dechert Schmitt, Anne-Marie; Singer, Robert A; Morken, James P.
Afiliação
  • Zhang M; Department of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.
  • Xu P; Department of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.
  • Vendola AJ; Department of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.
  • Allais C; Pfizer Worldwide Research and Development, Eastern Point Road, Groton, CT 06430, USA.
  • Dechert Schmitt AM; Pfizer Worldwide Research and Development, Eastern Point Road, Groton, CT 06430, USA.
  • Singer RA; Pfizer Worldwide Research and Development, Eastern Point Road, Groton, CT 06430, USA.
  • Morken JP; Department of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.
Angew Chem Int Ed Engl ; 61(30): e202205454, 2022 Jul 25.
Article em En | MEDLINE | ID: mdl-35587213
ABSTRACT
In this paper is described an easily synthesized chiral diazaborolidine that is inexpensive, stable, and provides excellent stereoselection across a number of reaction classes. These versatile compounds possess utility in four different classes of cycloaddition reactions, offering good yield and stereoselectivity. X-ray structure analysis provides insight about the origin of stereocontrol.
Palavras-chave
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Estados Unidos