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Co-existence of five- and six-coordinate iron(II) species captured in a geometrically strained spin-crossover Hofmann framework.
Xu, Luonan; Xie, Zixi; Zenere, Katrina A; Clegg, Jack K; Kenny, Elise; Rijs, Nicole J; Jameson, Guy N L; Kepert, Cameron J; Powell, Benjamin J; Neville, Suzanne M.
Afiliação
  • Xu L; School of Chemistry, The University of New South Wales, Sydney, New South Wales, 2052, Australia. s.neville@unsw.edu.au.
  • Xie Z; School of Chemistry, The University of Sydney, Sydney, New South Wales, 2006, Australia.
  • Zenere KA; School of Chemistry, The University of Sydney, Sydney, New South Wales, 2006, Australia.
  • Clegg JK; School of Chemistry and Molecular Biosciences, The University of Queensland, St Lucia, Queensland, 4072, Australia.
  • Kenny E; School of School of Mathematics and Physics, The University of Queensland, St Lucia 4072, Queensland, Australia.
  • Rijs NJ; School of Chemistry, The University of New South Wales, Sydney, New South Wales, 2052, Australia. s.neville@unsw.edu.au.
  • Jameson GNL; School of Chemistry, Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, 30 Flemington Road, Parkville, Victoria 3010, Australia.
  • Kepert CJ; School of Chemistry, The University of Sydney, Sydney, New South Wales, 2006, Australia.
  • Powell BJ; School of School of Mathematics and Physics, The University of Queensland, St Lucia 4072, Queensland, Australia.
  • Neville SM; School of Chemistry, The University of New South Wales, Sydney, New South Wales, 2052, Australia. s.neville@unsw.edu.au.
Dalton Trans ; 51(25): 9596-9600, 2022 Jun 27.
Article em En | MEDLINE | ID: mdl-35670370
Inclusion of an angular bridging ligand, 4,2':6',4''-terpyridine (TPy), into a Hofmann-type framework produces an irregular network in which six- and five-coordinate FeII species co-exist. The octahedral sites show thermally-induced spin-crossover (SCO) and the rare five-coordinate FeII sites are high-spin.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Austrália
Texto completo
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PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Austrália