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Sulfur-Phenolate Exchange: SuFEx-Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers.
Chao, Yang; Krishna, Akash; Subramaniam, Muthusamy; Liang, Dong-Dong; Pujari, Sidharam P; Sue, Andrew C-H; Li, Guanna; Miloserdov, Fedor M; Zuilhof, Han.
Afiliação
  • Chao Y; School of Pharmaceutical Science and Technology, Tianjin University, 92 Weijin Road, Tianjin, 300072, China.
  • Krishna A; School of Pharmaceutical Science and Technology, Tianjin University, 92 Weijin Road, Tianjin, 300072, China.
  • Subramaniam M; School of Pharmaceutical Science and Technology, Tianjin University, 92 Weijin Road, Tianjin, 300072, China.
  • Liang DD; Laboratory of Organic Chemistry, Wageningen University, Stippeneng 4, 6708WE, Wageningen, The Netherlands.
  • Pujari SP; Laboratory of Organic Chemistry, Wageningen University, Stippeneng 4, 6708WE, Wageningen, The Netherlands.
  • Sue AC; Department of Chemistry, Capital Normal University, Beijing, 100048, China.
  • Li G; Laboratory of Organic Chemistry, Wageningen University, Stippeneng 4, 6708WE, Wageningen, The Netherlands.
  • Miloserdov FM; College of Chemistry, Xiamen University, China.
  • Zuilhof H; Laboratory of Organic Chemistry, Wageningen University, Stippeneng 4, 6708WE, Wageningen, The Netherlands.
Angew Chem Int Ed Engl ; 61(36): e202207456, 2022 09 05.
Article em En | MEDLINE | ID: mdl-35819248
The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric synthesis and sustainable polymer production. Its wide scope further extends the usefulness of SuFEx and related click chemistries.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Polímeros / Enxofre Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article País de afiliação: China

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Polímeros / Enxofre Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article País de afiliação: China