C(sp3)-H oxidation and chlorination catalysed by a bioinspired pincer iron(III) complex.
Dalton Trans
; 51(31): 11620-11624, 2022 Aug 09.
Article
em En
| MEDLINE
| ID: mdl-35895115
ABSTRACT
A pincer iron(III) catalyst for the oxidation and chlorination of C(sp3)-H bonds was developed. Oxidation of a diagnostic substrate cis-decalin implies that a long-lived carbon-centred radical is involved. Mechanistic studies suggest that an Fe-oxo species could be responsible for the rate-determining C-H activation step. This report expands the scope of non-heme catalysts for C-H functionalisation.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Halogenação
/
Ferro
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2022
Tipo de documento:
Article
País de afiliação:
Estados Unidos