Limited Lithium Loading Promises Improved Lithium-Metal Anodes in Interface-Modified 3D Matrixes.

Confining Li metal in a three-dimensional (3D) matrix has been proven effective in improving the Li-metal anodes; however, in most studies, the loading of Li in the 3D matrix is far excessive, resulting in a dense bulk Li-metal anode with a low Li-utilization rate, forfeiting the effect of the 3D matrix. Here, we show that limiting the loading of Li metal within an interface-modified 3D carbon matrix not only increases the Li-utilization rate but also improves the electrochemical performance of the Li-metal anode. We use lithiophilic Fe2O3 granules anchored on a 3D carbon fiber scaffold to guide molten Li dispersion onto the fibers with controlled Li loading. Limiting Li loading maximizes the interface lithiophilic effect of the Fe2O3 granules while preserving sufficient space for electrolyte infusion, collectively ensuring uniform Li deposition and fast Li+ transport kinetics. The Li anode with limited Li dosage achieves remarkably improved Li-anode performances, including long lifespan, low voltage polarization, and low electrochemical resistance in both the symmetric cells and full cells. The improved electrochemical performance of the limited Li anode substantiates the importance to reduce Li loading from a fresh perspective and provides an avenue for building practical Li-metal batteries.