In-situ remediation of phosphogypsum in a cement-free pathway: Utilization of ground granulated blast furnace slag and NaOH pretreatment.
Chemosphere
; 313: 137412, 2023 Feb.
Article
em En
| MEDLINE
| ID: mdl-36455381
ABSTRACT
In-situ remediating phosphogypsum (PG) for cemented paste backfill (CPB) in the contaminated site is economic management for promoting sustainable developments in the phosphate industry. This study concerns the combined use of NaOH pretreatment and ground-granulated blast furnace slag (GGBFS) additives to promote the solidification/stabilization of PG with a lower carbon footprint pathway. According to physico-chemical analyses, the NaOH pretreatment effectively removed approximately 95% of F within the PG, which may originally be present as sparingly soluble fluorides or coexisting with silicates. The micro mineralogical characterization illustrates that the pretreatment can accelerate the early age hydration, with more hydration products observed, including calcium silicate hydrates and ettringite, effective F and P retention candidates. Whereas the incorporation of GGBFS plays an essential role in promoting the generation of additional cement hydrates at the following stages. The macro mechanical performance analysis indicates that the mixtures of pretreated-PG-OPC-GGBFS exhibit an excellent mechanical performance satisfying the design criteria. Subsequent elemental mapping and toxicity characteristic leaching procedures demonstrate that this combined approach has a competitive F and P immobilization ability compared to the typical OPC binder and individual GGBFS addition. The newly formed phases effectively controlled the concentration of F and P through adsorption, incorporation, or encapsulation. Objectively, the proposed methodology can be a promising candidate pathway for extrapolating the in-situ immobilization of PG. This study opens up new perspectives for synergetically recycling PG and GGBFS in a profitable and low carbon footprint way.
Palavras-chave
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Sulfato de Cálcio
Idioma:
En
Revista:
Chemosphere
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
China