Brønsted Acid/Base Site Isolated in a Pentanuclear Scaffold.

Tomoda, Misa; Kondo, Mio; Izu, Hitoshi; Masaoka, Shigeyuki

Tomoda, Misa; Kondo, Mio; Izu, Hitoshi; Masaoka, Shigeyuki.

Afiliação

Tomoda M; Division of Applied Chemistry Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan.
Kondo M; Department of Life and Coordination-Complex Molecular Science, Institute for Molecular Science (IMS), 5-1 Higashiyama, Myodaiji, Okazaki, Aichi, 444-8787, Japan.
Izu H; Department of Structural Molecular Sciences, SOKENDAI [The Graduate University for Advanced Studies] Shonan Village, Hayama, Kanagawa, 240-0193, Japan.
Masaoka S; Division of Applied Chemistry Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan.

Chemistry ; 29(7): e202203253, 2023 Feb 01.

Article em En | MEDLINE | ID: mdl-36507625

Palavras-chave

heterometallic pentanuclear complex; hydrogen evolution reaction; pH-insensitive Brønsted acid/base site; steric isolation of H+; thermodynamically metastable state

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Japão

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