In situ reduction of Cu nanoparticles on Mg-Al-LDH for simultaneous efficient catalytic transfer hydrogenation of furfural to furfuryl alcohol.
Chem Commun (Camb)
; 59(22): 3301-3304, 2023 Mar 14.
Article
em En
| MEDLINE
| ID: mdl-36846958
ABSTRACT
Herein, we report a simple and highly efficient approach for simultaneous in situ synthesis of Cu nanoparticles on Mg-Al-LDH (in situ reduced CuMgAl-LDH) from Cu-Mg-Al ternary LDH and catalytic transfer hydrogenation of furfural (FAL) to furfuryl alcohol (FOL) using isopropanol (2-PrOH) as a reducing agent and hydrogen source. The in situ reduced CuMgAl-LDH, especially Cu1.5Mg1.5Al1-LDH as a precursor, offered excellent performance for the catalytic transfer hydrogenation of FAL to FOL (achieving almost full conversion with 98.2% selectivity of FOL). Strikingly, the in situ reduced catalyst was robust and stable with a wide scope in the transfer hydrogenation of various biomass-derived carbonyl compounds.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article