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On the nucleation and fast reaction kinetics of 2D polymerisation with a 2-in-1 monomer.
Herrmann, Niklas; Martin, Cristina; Eyley, Samuel; Li, Yusen; Bilbao, Nerea; Rubio-Giménez, Víctor; Van der Auweraer, Mark; Thielemans, Wim; Chen, Long; Mali, Kunal S; De Feyter, Steven.
Afiliação
  • Herrmann N; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium. kunal.mali@kuleuven.be.
  • Martin C; Department of Physical Chemistry, Faculty of Pharmacy, University of Castilla-La Mancha, Albacete 02071, Spain.
  • Eyley S; Sustainable Materials Lab, Department of Chemical Engineering, KU Leuven, Campus Kulak Kortrijk, Etienne Sabbelaan 53, 8500 Kortrijk, Belgium.
  • Li Y; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China. longchen@jlu.edu.cn.
  • Bilbao N; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium. kunal.mali@kuleuven.be.
  • Rubio-Giménez V; Membrane Separations, Adsorption, Catalysis and Spectroscopy, Microbial and Molecular Systems, KU Leuven, 3001 Leuven, Belgium.
  • Van der Auweraer M; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium. kunal.mali@kuleuven.be.
  • Thielemans W; Sustainable Materials Lab, Department of Chemical Engineering, KU Leuven, Campus Kulak Kortrijk, Etienne Sabbelaan 53, 8500 Kortrijk, Belgium.
  • Chen L; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China. longchen@jlu.edu.cn.
  • Mali KS; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium. kunal.mali@kuleuven.be.
  • De Feyter S; Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium. kunal.mali@kuleuven.be.
Chem Commun (Camb) ; 59(60): 9211-9214, 2023 Jul 25.
Article em En | MEDLINE | ID: mdl-37409590
We report on the fast reaction kinetics of an imine based 2D polymer (2DP) formed from a single monomer carrying both aldehyde and amine groups. Our results point towards a direct monomer-to-crystalline polymer transition without an amorphous intermediate.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Bélgica

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Bélgica