Efficient photodegradation of paraquat herbicide over TiO2-WO3 heterojunction embedded in diatomite matrix and process optimization.

ABSTRACT

Photodegradation of paraquat herbicide was assessed over several TiO2-WO3 heterojunctions embedded in the diatomite matrix. The characterization results indicated that WO3 embedding in the TiO2 decorated-diatomite matrix could not only enhance the adsorption capacity, visible-light response, and distribution of semiconductor species but also lessen the recombination rate and band gap energy. These characteristics were more noticeable as 5 wt.% of WO3 was embedded. Despite better optical properties of immobilized TiO2-WO3 nanocomposites, overloading WO3 generally alleviates the synergetic effect of tungsten due to surface coverage of diatomite matrix and, subsequently, the significant attenuation of textural properties, more formation of agglomerations and defects as trapping centers in the oxidation sites of heterostructures, and also, less likely of forming TiO2-WO3 heterojunction. In accordance with characterization results, the highest UV-photodegradation of paraquat was attained over heterostructured nanocomposite containing 5 wt.% WO3 (T25-W5/Di). The effects of significant operating parameters were also investigated, modeled, and optimized using response surface methodology (RSM)-central composite design (CCD). Under optimized operation conditions, the experimental removal efficiency of paraquat reached 97.1 and 80% using UV and simulated solar light, respectively. Moreover, the reusability results confirm the sustained activity of the T25-W5/Di nanocomposite.