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Kinetics of ester-105 degradation by La/TiO2 photocatalysis.
Zhu, Sipin; Chen, Chunfei; Wang, Zhaopeng; Wang, Chunying; Luo, Xianping.
Afiliação
  • Zhu S; Jiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Ganzhou, China.
  • Chen C; Faculty of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, China.
  • Wang Z; The Peoples Government of Tangnan Township, Nanchang, China.
  • Wang C; Jiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Ganzhou, China.
  • Luo X; Faculty of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, China.
Article em En | MEDLINE | ID: mdl-37916440
Lanthanum-doped titanium (La/TiO2) nano-photocatalysts were prepared using the sol-gel method and characterized by X-ray diffraction (XRD), zeta potential, and low-temperature nitrogen adsorption analyses. Ester-105, a flotation collector from beneficiation wastewater, was chosen as the target pollutant. The influence of the initial ester-105 concentration, pH, and photocatalyst dosage on the photocatalytic degradation of ester-105 was investigated. To examine the kinetics of the adsorption and photocatalytic degradation of ester-105, a Langmuir adsorption model and Langmuir-Hinshelwood kinetic models were established and discussed. The synthesized photocatalyst comprised anatase-phase TiO2, with an isoelectric point of pH = 6.5, specific surface area of 56.1626 m2·g-1, and average pore size of 7.78 nm. The maximum adsorption and the adsorption equilibrium constant of La/TiO2 for ester-105 were determined as 0.338 mg·g-1 and 1.008 L·mg-1, respectively. The first-order kinetic reaction rate constant (k) exhibited a linear relationship with the initial ester-105 concentration. The optimal pH for ester degradation was theoretically determined to be 6.95, and the optimum photocatalyst dosage was found to be 0.2739 g·L-1. Experiments confirmed that the photocatalytic degradation of ester-105 using La/TiO2 followed the Langmuir-Hinshelwood kinetics model, thereby providing a theoretical foundation for the photocatalytic degradation of ester-105 for industrial application.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Titânio / Águas Residuárias Idioma: En Revista: J Environ Sci Health A Tox Hazard Subst Environ Eng Assunto da revista: TOXICOLOGIA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: China

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Titânio / Águas Residuárias Idioma: En Revista: J Environ Sci Health A Tox Hazard Subst Environ Eng Assunto da revista: TOXICOLOGIA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: China