Hydrazide Schiff base Compound Containing Triphenylphosphonium Units for Fluorescence Sensing of Al3+ and its real Sample Applications.

Al3+ excess in the body can cause many diseases. The development of chemosensors for the detection of Al3+ is therefore highly desirable. A hydrazide Schiff base compound containing triphenylphosphonium units (ER) was prepared and used as fluorescence turn-on sensor for the sensing of Al3+. Detection of Al3+ among various metals has been achieved successfully through the formation of Al3+-ligand coordination complexes. To detect Al3+, the "turn on" property of the fluorogenic chemosensor was investigated. Fluorescence sensing studies were carried out in CH3OH-Water (v/v, 9/1, pH 7.0) at λem = 528 nm. The LOD for sensing of Al3+ was found to be 0.129 µM. Using Job's graph, the stoichiometric ratio of ER- Al3+ was determined to be 1:1. The binding constant was determined to be 1.7 × 107 M-1 between Al3 + and the chemosensor ER. Finally, the determination of Al3+ in real herbal teas was carried out by using the sensing function of the chemosensor ER.