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Synthesis and Photophysical Properties of Silole-Fused Cycloparaphenylenes.
Wang, Yedong; Huang, Shiqing; Zhang, Zengyu; Yan, Xiaoyu.
Afiliação
  • Wang Y; Department of Chemistry, Key Laboratory of Advanced Light Conversion Materials and Biophotonics Department of Chemistry, Renmin University of China, Beijing 100872, People's Republic of China.
  • Huang S; Department of Chemistry, Key Laboratory of Advanced Light Conversion Materials and Biophotonics Department of Chemistry, Renmin University of China, Beijing 100872, People's Republic of China.
  • Zhang Z; Department of Chemistry, Key Laboratory of Advanced Light Conversion Materials and Biophotonics Department of Chemistry, Renmin University of China, Beijing 100872, People's Republic of China.
  • Yan X; Department of Chemistry, Key Laboratory of Advanced Light Conversion Materials and Biophotonics Department of Chemistry, Renmin University of China, Beijing 100872, People's Republic of China.
J Org Chem ; 89(1): 681-686, 2024 Jan 05.
Article em En | MEDLINE | ID: mdl-38065576
ABSTRACT
Herein, we report the introduction of a silole unit into cycloparaphenylenes (CPPs), and two compounds [12]Si3CPP and [16]Si4CPP are obtained by a platinum- and gold-mediated cyclooligomerization strategy. Their optical and electronic properties are studied by UV-vis absorption and fluorescence spectra, which show red shifts and higher photoluminescence quantum yields (PLQYs) compared with the corresponding CPPs.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2024 Tipo de documento: Article