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Phenothiazine cyclic hexamers: synthesis, properties, and complexation behavior with C60.
Yamamoto, Koji; Tsutsui, Kanta; Tanuma, Miho; Ito, Kaname; Wakamatsu, Kan; Yamamoto, Koji; Nakamura, Yosuke.
Afiliação
  • Yamamoto K; Department of Pharmaceutical Sciences, Shujitsu University, 1-6-1 Nishigawara, Okayama 703-8516, Japan. yamakou@shujitsu.ac.jp.
  • Tsutsui K; Division of Molecular Science, Faculty of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan. nakamura@gunma-u.ac.jp.
  • Tanuma M; Division of Molecular Science, Faculty of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan. nakamura@gunma-u.ac.jp.
  • Ito K; Division of Molecular Science, Faculty of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan. nakamura@gunma-u.ac.jp.
  • Wakamatsu K; Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, Kita-ku, Okayama 700-0005, Japan.
  • Yamamoto K; Department of Applied Chemistry, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Kanagawa 239-8686, Japan.
  • Nakamura Y; Division of Molecular Science, Faculty of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan. nakamura@gunma-u.ac.jp.
Chem Commun (Camb) ; 60(16): 2220-2223, 2024 Feb 20.
Article em En | MEDLINE | ID: mdl-38314630
ABSTRACT
Phenothiazine cyclic hexamers linked at the 3,7-positions were synthesized. Effects of the cyclic structure as well as substituent effects of the nitrogen atom were disclosed. Furthermore, the cyclic hexamer encapsulated C60 inside the ring in a 1 1 ratio giving a Saturn-type complex in solution. The structure and interactions were discussed based on DFT calculations.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Japão

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Japão