Diversity of oxidation state in copper complexes with phenolate ligands.
Dalton Trans
; 53(9): 3911-3929, 2024 Feb 27.
Article
em En
| MEDLINE
| ID: mdl-38319292
ABSTRACT
The phenoxyl radical binding copper complexes have been widely developed and their detailed geometric and electronic structures have been clarified. While many one-electron oxidized CuII-phenolate complexes have been reported previously, recent studies of the Cu-phenolate complexes proceed toward elucidation of the complexes with other oxidation states, such as the phenoxyl radical binding CuI complexes and CuIV-phenolate complexes in the formal oxidation state. This Perspective focuses on new aspects of the properties and reactivities of various Cu-phenolate and Cu-phenoxyl radical complexes with emphasis on the relationship between geometric and electronic structures.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Japão