GeV4S8: a Novel Bimetallic Sulfide for Robust and Fast Potassium Storage.
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; 20(29): e2311638, 2024 Jul.
Article
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| MEDLINE
| ID: mdl-38342598
ABSTRACT
Potassium-ion batteries (PIBs) have attracted much attention due to their low production cost and abundant resources. Germanium is a promising alloying-type anode with a high theoretical capacity for PIBs, yet suffering significant volume expansion and sluggish potassium-ion transport kinetics. Herein, a rational strategy is formulated to disperse Ge atoms into transition metal V-S sulfide frameworks to form a loosely packed and metallic GeV4S8 medium. The theoretical prediction shows that GeV4S8 is conducive to the adsorption and diffusion of K+. The V-S frameworks provide fast ion/electron diffusion channels and also help to buffer the volume expansion during K+ insertion. In situ and ex situ characterizations manifest that KGe alloy clusters are constrained and dispersed by potassiated VS2 topological structure during discharging, and revert to the original GeV4S8 after charging. Consequently, as a novel anode for PIBs, GeV4S8 provides a high specific capacity of ≈400 mAh g-1 at 0.5 C, maintaining 160 mAh g-1 even at 12.5 C and ≈80% capacity after 1000 cycles at 5 C, superior to most of the state-of-the-art anode materials. The proposed strategy of combining alloy and intercalation dual-functional units is expected to open up a new way for high-capacity and high-rate anode for PIBs.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Small
Assunto da revista:
ENGENHARIA BIOMEDICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
China