NHC-ligated indenyl- and fluorenyl-substituted Alanes and Gallanes: synthons towards indenyl- and fluorenyl-bridged (AlC)n-heterocycles (n = 2,3).
Dalton Trans
; 53(13): 5932-5946, 2024 Mar 26.
Article
em En
| MEDLINE
| ID: mdl-38456748
ABSTRACT
Indenyl-(Ind) and fluorenyl-(Fl) substituted NHC-stabilized alanes and gallanes (NHC)·EH2R 1-12 (NHC = IiPrMe, IiPr, IMeMe; E = Al, Ga; R = Ind, Fl) were prepared via reaction of the corresponding NHC-iodoalanes and -gallanes with LiInd and LiFl, respectively. Analogously, the alane adducts with two Ind/Fl substituents (NHC)·AlHR213-18 (NHC = IiPrMe, IiPr, IMeMe; R = Ind, Fl) were obtained by using two equivalents of LiInd/LiFl. Elimination of indene and fluorene was induced thermally affording unusual dimeric and trimeric NHC-alane adducts {(NHC)·AlH2}2-µ-Fl 19-20 and {(NHC)·AlH-µ-R}n21-23 (R = Ind, Fl; n = 2, 3) with bridging indenyl and fluorenyl ligands.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Alemanha