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ortho-Alkynyl Benzyl Alcohols as C6 Synthons in Regioselective Construction of Polysubstituted Naphthalenes.
Wei, Xuemei; Cai, Tao; Zhang, Zhebing; Luo, Yanjuan; Shang, Tianbo; Shen, Hualiang; Xu, Huiting; Yu, Lemao; Luo, Xiang; Yu, Guoqi; Shen, Runpu.
Afiliação
  • Wei X; College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, China.
  • Cai T; Zhejiang Engineering Research Center of Fat-Soluble Vitamin, Shaoxing University, Shaoxing312000, China.
  • Zhang Z; College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, China.
  • Luo Y; Zhejiang Engineering Research Center of Fat-Soluble Vitamin, Shaoxing University, Shaoxing312000, China.
  • Shang T; College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, China.
  • Shen H; College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, China.
  • Xu H; Zhejiang Engineering Research Center of Fat-Soluble Vitamin, Shaoxing University, Shaoxing312000, China.
  • Yu L; College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, China.
  • Luo X; Zhejiang Engineering Research Center of Fat-Soluble Vitamin, Shaoxing University, Shaoxing312000, China.
  • Yu G; College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, China.
  • Shen R; Zhejiang Engineering Research Center of Fat-Soluble Vitamin, Shaoxing University, Shaoxing312000, China.
J Org Chem ; 89(11): 7804-7811, 2024 Jun 07.
Article em En | MEDLINE | ID: mdl-38738759
ABSTRACT
A straightforward methodology for the assembly of polysubstituted naphthalenes from ortho-alkynyl benzyl alcohols, enabled by using catalytic amounts of Tf2O, has been developed. This transformation not only features transition-metal free and without using other bases and additives but also provides a new synthetic application for ortho-alkynyl benzyl alcohols, i.e., as C6 synthons for the construction of PAHs.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China