Preferential crystallization of (±)-pinenyllithium·TMEDA.
Acta Crystallogr C Struct Chem
; 80(Pt 7): 297-301, 2024 Jul 01.
Article
em En
| MEDLINE
| ID: mdl-38899749
ABSTRACT
(±)-Pinenyllithium·TMEDA or (tetramethylethylenediamine-κ2N,N')(η3-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptyl)lithium, [Li(C10H15)(C6H16N2)], is readily prepared from ß-pinene, butyllithium and TMEDA, and the racemic material preferentially crystallizes even from 964 (92%â
ee) mixtures of (-)- and (+)-ß-pinene, respectively. The structure is monomeric, with the geminal-dimethyl bridge of the bicyclic structure shielding one face of the allyl system, restricting the lithium to the opposite face and preventing the Li-allyl-Li aggregation observed with some other allyllithium systems. The symmetry of the allyl system, bond lengths, bond angles and out-of-plane deviations are compared to existing structures. In addition, a much older structure of this complex is compared to this very recent one.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr C Struct Chem
/
Acta Crystallogr. C. Struct. Chem
/
Acta crystallographica. Section C, Structural chemistry. (Online)
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Estados Unidos