Flexible and Dynamic Light-Guided Electrochemiluminescence for Spatiotemporal Imaging of Photoelectrochemical Processes on Hematite.
Anal Chem
; 96(28): 11146-11154, 2024 Jul 16.
Article
em En
| MEDLINE
| ID: mdl-38917341
ABSTRACT
Here, we report an electrochemiluminescence (ECL)-based approach for imaging of local photoelectrochemical processes on hematite in a spatially and temporally controlled manner. The local processes were guided by flexible and dynamic light illumination, not requiring any prepatterned conductive features or photomasks, with a digital micromirror device (DMD). The imaging approach was based on light-addressable electrochemical reactions on hematite, resulting in photoinduced ECL emission for spatiotemporally resolved imaging of photoelectrochemical processes selectively guided by light illumination. After clarifying the capability of hematite as a photosensitive electrode, we validated that the illuminated hematite exhibited stable light-guided ECL emission in correspondence with the illuminated area, with a spatial resolution of 0.8 µm and a temporal resolution of 1 µs, even over a long period of 6 h. More importantly, this study exemplified the simple yet effective ECL-based approach for electrochemical visualization of local photoelectrochemical processes guided by flexible and dynamic adjustment of light illumination in a spatiotemporally controlled way.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Anal Chem
Ano de publicação:
2024
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Article