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Supramolecular Complexation-enhanced CO2 Chemisorption in Amine-derived Sorbents.
Li, Errui; Li, Bo; Ganesan, Arvind; Qiu, Liqi; Jiang, De-En; Mahurin, Shannon M; Pramanik, Subhamay; Popovs, Ilja; Yang, Zhenzhen; Dai, Sheng.
Afiliação
  • Li E; The University of Tennessee Knoxville, Department of Chemistry, UNITED STATES.
  • Li B; Vanderbilt University, Department of Chemical and Biomolecular Engineering, UNITED STATES.
  • Ganesan A; Oak Ridge National Laboratory, Chemical Sciences Division, UNITED STATES.
  • Qiu L; The University of Tennessee Knoxville, Department of Chemistry, 2641 Osprey Vista Way, KNOXVILLE, KNOXVILLE, UNITED STATES.
  • Jiang DE; Vanderbilt University, Department of Chemical and Biomolecular Engineering, UNITED STATES.
  • Mahurin SM; Oak Ridge National Laboratory, Chemical Sciences Division, UNITED STATES.
  • Pramanik S; Oak Ridge National Laboratory, Chemical Sciences Division, UNITED STATES.
  • Popovs I; Oak Ridge National Laboratory, Chemical Sciences Division, UNITED STATES.
  • Yang Z; Oak Ridge National Laboratory, Chemical Sciences Division, UNITED STATES.
  • Dai S; Oak Ridge National Laboratory, Chemical Sciences Division, 1 Bethel Valley Rd., PO BOX 2008 MS6201, 37831, Oak Ridge, UNITED STATES OF AMERICA.
Chemistry ; : e202402137, 2024 Jun 26.
Article em En | MEDLINE | ID: mdl-38924754
ABSTRACT
A supramolecular complexation approach is developed to improve the CO2 chemisorption performance of solvent-lean amine sorbents. Operando spectroscopy techniques reveal the formation of carbamic acid in the presence of a crown ether. The reaction pathway is confirmed by theoretical simulation, in which the crown ether acts as proton acceptor and shuttle to drive the formation and stabilization of carbamic acid. Improved CO2 capacity and diminished energy consumption in sorbent regeneration was achieved.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Estados Unidos