A Covalent Organic Nanoribbon: Preparation, Single-Crystal Structure with Chinese Luban Lock Configuration, and Photocatalytic Behavior.
Angew Chem Int Ed Engl
; : e202411018, 2024 Jun 27.
Article
em En
| MEDLINE
| ID: mdl-38932606
ABSTRACT
The multiple mortise-and-tenon joint parts are the core factors to provide the structural stability and diversity of Chinese Luban locks; however, constructing such structures is very challenging. Herein, single crystals of a covalent organic nanoribbon (named CityU-27) are prepared through the assembly of hexahydroxytriphenylene (HHTP), 4,4'-vinylenedipyridine (BYE), and phenylboronic acid (BA) together through dative boronânitrogen (BâN) bonds. The single-crystal X-ray diffraction analysis indicates that CityU-27 has a covalent organic nanoribbon structure, where each nanoribbon forms multiple and tight π-π interactions with four neighboring others to generate a Luban lock-like configuration. CityU-27 has been demonstrated to be an efficient photocatalyst in a one-pot tandem reaction of hydrogen evolution reaction (HER) and semi-hydrogenation reaction of alkynes in series to produce olefins without any additional photosensitizers and co-catalysts (metal-free).
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MEDLINE
Idioma:
En
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Angew Chem Int Ed Engl
Ano de publicação:
2024
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Article