Evaluating the potential of Abelmoschus esculentus, Solanum melongena, and Capsicum annuum spp. for nutrient and microbial reduction from wastewater in hybrid constructed wetland.

Utilizing engineered wetlands for the cultivation of vegetables can help to overcome the problems of water and food scarcity. These wetlands are primarily designed for wastewater treatment, and their efficiency and effectiveness can be improved by selecting an appropriate substrate. To investigate the potential for nutrient and microbial removal, the Abelmoschus esculentus, Solanum melongena, and Capsicum annuum L. plants were selected to grow in a hybrid constructed wetland (CW) under natural conditions. The removal efficiency of the A. esculentus, S. melongena, and C. annuum L. in the CW system varied between 59.8 to 68.5% for total phosphorous (TP), 40.3 to 53.1% for ammonium (NH4+), and 33.6 to 45.1% for total nitrogen (TN). The influent sample contained multiple pathogenic bacteria, including Alcaligenes faecalis, Staphylococcus aureus, and Escherichia coli, with Capsicum annuum exhibiting a positive association with 7 of the 11 detected species, whereas microbial removal efficiency was notably higher in the S. melongena bed, potentially attributed to temperature variations and plant-facilitated oxygen release rates. While utilizing constructed wetlands for vegetable cultivation holds promising potential to address the disparity between water and food supply and yield various environmental, economic, and social benefits, it is crucial to note that the wastewater source may contain heavy metals, posing a risk of their transmission to humans through the food chain.

Modeling and optimizing of an actual municipal sewage plant: A comparison of diverse multi-objective optimization methods.

The activated sludge process of an actual municipal sewage treatment plant was systematically modeled, calibrated, and verified in this study. Identified multi-objective optimization (MOO) methods were employed to optimize the process parameters of the validated model, and the optimal MOO algorithm was obtained by comparing Pareto solution sets. The optimization model consisted of three key evaluation indicators (objective functions), which are the average effluent quality (AEQ), overall cost index (OCI), and total volume (TV) of the biochemical tank, along with 12 more process parameters (decision variables). Three optimization algorithms, i.e., adaptive non-dominated sorting genetic algorithm III (ANSGA-III), non-dominated sorting genetic algorithm II (NSGA-II), and particle swarm algorithm (PSO), were adopted using MATLAB. The comparison of these algorithms demonstrated that the ANSGA-III algorithm had better Pareto solution sets under the triple objective optimization, and the effluent quality of COD, TN, NH4+-N, and TP after optimization decreased by 2.22, 0.47, 0.13, and 0.02 mg/L, respectively. Additionally, the simulated AEQ was reduced by 13% compared to the original effluent, and the OCI and TV decreased from 21,023 kWh d-1 and 17,065 m3 to 20,226 kWh d-1 and 16,530 m3, respectively. The reported ANSGA-III algorithm and the proposed multi-objective method have a promising ability for energy conservation, emission reduction, and upgrading of municipal sewage treatment plants.

Stability, aggregation, and sedimentation behaviors of typical nano metal oxide particles in aqueous environment.

The wide use of nano metal oxide particles (NMOPs) brings about their inevitable release into the water environment, affecting the environment and human health. Therefore, the stability, aggregation, and sedimentation process of four typical NMOPs (ZnO NPs, CeO2 NPs, TiO2 NPs, and CuO NPs) were investigated in artificial water and real municipal sewage to reveal their complicated behavior. Results showed that NMOPs aggregated at the pH of zero-charge point, and their hydrodynamic diameters and aggregation rates could reach the maximum values. The hydrodynamic diameters and aggregation rates of ZnO NPs, CeO2 NPs, TiO2 NPs, and CuO NPs at the zero-charge point were 617, 1760, 870, 1502 nm, and 31.7, 1158.1, 48.3, 115.7 nm/min, respectively. In addition, the dissolution of NMOPs led to the sedimentation rates under acidic conditions being much lower than those under neutral and alkaline conditions. The aggregation and sedimentation performance of NMOPs were affected by not only pH but also ionic strength (IS) and species. The aggregation rates of NMOPs increased with the increase of IS (0-10 mM), and the maximum aggregation rate of CeO2 NPs was 470.1 nm/min (pH = 7 and CaCl2 = 10 mM). According to Coulomb's law, divalent cations (Mg2+, Ca2+) were more competitively adsorbed on the surface of NMOPs than monovalent cations (K+, Na+), which increased the zeta potential and aggregation rate of NMOPs. Furthermore, the NMOPs were easier to aggregate in municipal sewage because of the homogeneous aggregation between nanoparticles and heterogeneous aggregation with natural colloids. The total interaction energy between NMOPs was calculated by the classical Derjaguin-Landau-Verwey-Overbeek (DLVO) theoretical formula, which was consistent with the experimental results.

Nutrient removal in hybrid constructed wetlands: spatial-seasonal variation and the effect of vegetation.

Constructed wetlands (CWs) are an aesthetic and sustainable form to treat wastewater, however, their performance can be increased by improving a number of factors. The pilot-scale hybrid constructed wetland (CW) system was the combination of constructed floating treatment wetlands (CFWs) and horizontal subsurface flow constructed wetlands (HSFCWs); operated for a year and covered all seasons. The research was conducted to investigate the performance of the CW system regarding water depth, spatial, and seasonal removal of pollutants. Nine economical plants species were selected and divided into four groups to grow in CW-I to CW-IV, respectively. Removal increased along the bed and most of the total phosphorus (TP) removal occurred in the second bed, whereas total nitrogen (TN) and ammonium (NH4) removal were associated with the plant root system and biomass. Optimum removal of nutrients with respect to water depth was at 35 cm. TN and NH4 removal patterns were similar in different CWs. TN and NH4 removal were higher during summer compared to winter; only CW-IV showed the opposite trend.

An integrated process for struvite recovery and nutrient removal from ship domestic sewage.

Marine pollution caused by the untreated and substandard discharge of ship domestic sewage has received widespread attention. A novel integrated process for struvite recovery and nutrient removal from ship domestic sewage (SRNR-SDS) based on seawater magnesium source was developed in this study. Removal efficiencies of the total nitrogen (TN) and total phosphorus (TP) for the activated sludge unit in SRNR-SDS process were approximately 67.61% and 41.35%, respectively, under the salinity of 7.85 g/L. The coupling-induced struvite crystallization unit significantly improved the removal efficiency of TN and TP, and the scanning electron microscopy and X-ray diffraction demonstrated that magnesium ammonium phosphate (MAP) crystals were successfully formed on the surface of zeolite. The SRNR-SDS process had an ideal performance for pollutant removal and MAP recovery under the optimal hydraulic retention time of 20 h. The effluent concentrations of COD, NH4+-N, TN and TP in SRNR-SDS process were approximately 34.73 mg/L, 4.31 mg/L, 10.07 mg/L and 0.23 mg/L, respectively, which meet the Chinese and international ship sewage discharge standards. SRNR-SDS process has obvious environmental, social and economic benefits, which could save 6.20%∼57.14% of the operation cost of ship domestic sewage treatment via MAP recovery. The results could provide theoretical and technical support for the development and application of ship sewage treatment process with the functions of pollutant removal and resource recovery.

Effects of nano metal oxide particles on denitrifying phosphorus removal system: Potential stress mechanism and recovery strategy.

The accumulation of nano metal oxide particles (NMOPs) in municipal sewage treatment systems harms the microbial community and its metabolism in activated sludge system, resulting in the degradation of its pollutants removal performance. In this work, the stress effect of NMOPs on the denitrifying phosphorus removal system was systematically investigated in terms of pollutants removal performance, key enzyme activities, microbial community diversity and abundances, and intracellular metabolites. Among the ZnO NPs, TiO2 NPs, CeO2 NPs, and CuO NPs, the ZnO NPs showed the most significant impacts with the chemical oxygen demand, total phosphorus, and nitrate nitrogen removal ratio decreased from above 90 % to 66.50 %, 49.13 %, and 57.11 %, respectively. The addition of surfactants and chelating agents could relieve the toxic effect of NMOPs on the denitrifying phosphorus removal system, and the chelating agents were more effective than surfactants in performance recovery. After adding ethylene diamine tetra acetic acid, the removal ratio of chemical oxygen demand, total phosphorus, and nitrate nitrogen under ZnO NPs stress was restored to 87.31 %, 88.79 %, and 90.35 %, respectively. The study provides valuable knowledge to better understand the impacts and stress mechanism of NMOPs on activated sludge systems and provides a solution to recover the nutrients removal performance of denitrifying phosphorus removal system under NMOPs stress.

Construction of double tube granular sludge microbial fuel cell and its characteristics and mechanism of azo dye degradation.

Microbial fuel cells (MFCs) can obtain electrical energy from extensive organic matter and complete wastewater treatment at the same time. The principal purpose of the research is to find a solution to the biodegradation of X-3B in a double tube MFC with graphite fiber brush as the anode and carbon cloth as the cathode. The anaerobic, aerobic, and electrochemical processes in the MFC were investigated. The effects of dye concentration and circuit connectivity on the performances of MFCs were explored. The degradation efficiency of X-3B in the anode region (85.56%) was higher than that in the cathode region (14.16%) within 24 h under the optimal voltage of 0.43 V, indicating a synergistic effect between electrode reaction and biodegradation. The power density increased from 12.12 mW/m3 to 60.45 mW/m3 with the addition of X-3B from 50 to 200 mg/L, because of the reduced ohmic and polarization resistance. Intermediate productions such as aniline were manufactured with the conjugated double bond of X-3B broken, and the intermediates were degraded into small molecular products like phenol during further degradation processes. Moreover, dye concentration and circuit connection had significant effects on the relative abundance of the microbial community at phylum and genus levels. In general, MFC is a good approach to energy generation and azo dye treatment at the same time.

Simultaneous denitrification and phosphorus removal: A review on the functional strains and activated sludge processes.

Eutrophication has attracted extensive attention owing to its harmful effects to the organisms and aquatic environment. Studies on the functional microorganisms with the ability of simultaneously nitrogen (N) and phosphorus (P) removal is of great significance for alleviating eutrophication. Thus far, several strains from various genera have been reported to accomplish simultaneous N and P removal, which is primarily observed in Bacillus, Pseudomonas, Paracoccus, and Arthrobacter. The mechanism of N and P removal by denitrifying P accumulating organisms (DPAOs) is different from the traditional biological N and P removal. The denitrifying P removal (DPR) technology based on the metabolic function of DPAOs can overcome the problem of carbon source competition and sludge age contradiction in traditional biological N and P removal processes and can be applied to the treatment of urban sewage with low C/N ratio. This paper reviews the mechanism of N and P removal by DPAOs from the aspect of the metabolic pathways and enzymatic processes. The research progress on DPR processes is also summarized and elucidated. Further research should focus on the efficient removal of N and P by improving the performance of functional microorganisms and development of new coupling processes. This review can serve as a basis for screening DPAOs with high N and P removal efficiency and developing new DPR processes in the future.

Impact of storm water on groundwater quality below retention/detention basins.

Groundwater from 33 monitoring of peripheral wells of Karachi, Pakistan were evaluated in terms of pre- and post-monsoon seasons to find out the impact of storm water infiltration, as storm water infiltration by retention basin receives urban runoff water from the nearby areas. This may increase the risk of groundwater contamination for heavy metals, where the soil is sandy and water table is shallow. Concentration of dissolved oxygen is significantly low in groundwater beneath detention basin during pre-monsoon season, which effected the concentration of zinc and iron. The models of trace metals shown in basin groundwater reflect the land use served by the basins, while it differed from background concentration as storm water releases high concentration of certain trace metals such as copper and cadmium. Recharge by storm water infiltration decreases the concentration and detection frequency of iron, lead, and zinc in background groundwater; however, the study does not point a considerable risk for groundwater contamination due to storm water infiltration.