RESUMO
Contact electrification (CE) in water has attracted much attention, owing to its potential impacts on the chemical reactions, such as the recent discovery of spontaneous generation of hydrogen peroxide (H2O2) in water microdroplets. However, current studies focus on the CE of bulk water, the measurement of CE between micrometer-size water droplets is a challenge and its mechanism still remains ambiguous. Here, a method for quantifying the amount of charge carried by the water microdroplets produced by ultrasonic atomization is proposed. In the method, the motions of water microdroplets in a uniform electric field are observed and the electrostatic forces on the microdroplets are calculated based on the moving speed of the microdroplets. It is revealed that the charge transfer between water microdroplets is size-dependent. The large microdroplets tend to be positively charged while the small microdroplets tend to receive negative charges, implying that the negative charges transfer from large microdroplets to the small microdroplets during ultrasonic atomization. Further, a theoretical model for microdroplets charging is proposed, in which the curvature-induced surface potential/energy difference is suggested to be responsible for the charge transfer between microdroplets. The findings show that the electric field strength between two microdroplets with opposite charges during separation is strong enough to convert OHâ to OH*, providing evidence for the CE-induced spontaneous generation of H2O2 in water microdroplets.
RESUMO
Shelter forests (or shelter-belts), while crucial for climate regulation, lack monitoring systems, e.g., Internet of Things (IoT) devices, but their abundant wind energy can potentially power these devices using the trees as mounting points. To harness wind energy, an omnidirectional fluid-induced vibration triboelectric nanogenerator (OFIV-TENG) has been developed. The device is installed on shelter forest trees to harvest wind energy from all directions, employing a fluid-induced vibration (FIV) mechanism (fluid-responding structure) that can capture and use wind energy, ranging from low wind speeds (vortex vibration) to high wind speeds (galloping). The rolling-bead triboelectric nanogenerator (TENG) can efficiently harvest energy while minimizing wear and tear. Additionally, the usage of double electrodes results in an effective surface charge density of 21.4 µC m-2 , which is the highest among all reported rolling-bead TENGs. The collected energy is utilized for temperature and humidity monitoring, providing feedback on the effect of climate regulation in shelter forests, alarming forest fires, and wireless wind speed warning. In general, this work provides a promising and rational strategy, using natural resources like trees as the supporting structures, and shows broad application prospects in efficient energy collection, wind speed warning, and environmentally friendliness.
RESUMO
The triboelectric nanogenerator (TENG) is regarded as an effective strategy for harvesting energy from raindrops, and is a complementary solution with solar cells to achieve all-weather energy harvesting and sustainable energy supply. However, due to the irregularity of natural rainfalls in the volume, frequency, density, and location, designing high-efficiency raindrop TENG (R-TENG) arrays faces great challenges. In this work, a highly transparent, large-area, and high-efficiency R-TENG array with rational material choice, electrode structure, and array distribution is developed for efficiently harvesting irregular raindrop energy. The problem of electrical signal cancellation among adjacent raindrops can be fully avoided, as viewed from the high-resolution space-time analyses of high-speed camera and electrical signal characteristics. With the rationally designed electrode instead of multiple complex electrodes, all charges can be exported by the R-TENG array in a simulated irregular raindrop scenario. Moreover, it is demonstrated that the R-TENG possesses higher average power density (40.80 mW m-2 ) than that of the solar cell (37.03 mW m-2 ) in rainy condition. Additionally, a self-powered wireless light-intensity-monitoring system is demonstrated for real-time and all-day weather monitoring. This work provides useful guidance for designing high-efficiency TENG arrays integrated with solar panels for harvesting irregular raindrop energy and solar energy.
RESUMO
The monitoring of space debris assumes paramount significance to ensure the sustainability and security of space activities as well as underground bases in outer space. However, designing a wide range monitoring system with easy fabrication, low power, and high precision remains an urgent challenge under the scarcity of materials and extreme environment conditions of outer space. Here, we designed a one-piece, robust, but flexible, and repairable 3D metal-printed triboelectric nanogenerator (FR-TENG) by incorporating the advantages of standardization and customization of outer space 3D metal printing. Inspired by the structure of hexagonal and pangolin scales, a curved structure is ingeniously applied in the design of 3D printed metal to adapt different curved surfaces while maintaining superior compressive strength, providing excellent flexibility and shape adaptability. Benefiting from the unique structural design, the FR-TENG has a minimum length of 1 cm with a weight of only 3.5 g and the minimum weight resolution detected of 9.6 g, with a response time of 20 ms. Furthermore, a multichannel self-powered collision monitoring system has been developed to monitor minor collisions, providing warnings to determine potential impacts on the space station and bases surfaces. The system may contribute to ensuring the successful completion of space missions and providing a safer space environment for the exploration of extraterrestrial life and the establishment of underground protective bases.
RESUMO
Real-time monitoring of flow turbulence is very difficult but extremely important in fluid dynamics, which plays an important role in flight safety and control. Turbulence can cause airflow to detach at the end of the wings, potentially resulting in the aerodynamic stall of aircraft and causing flight accidents. Here, we developed a lightweight and conformable system on the wing surface of aircraft for stall sensing. Quantitative data about airflow turbulence and the degree of boundary layer separation are provided in situ using conjunct signals provided by both triboelectric and piezoelectric effects. Thus, the system can visualize and directly measure the airflow detaching process on the airfoil, and senses the degree of airflow separation during and after a stall for large aircraft and unmanned aerial vehicles.
RESUMO
The triboelectric nanogenerator (TENG) developed by Z. L. Wang's team to harvest random mechanical energy is a promising new energy source for distributed sensing systems in the new era of the internet of things (IoT) and artificial intelligence (AI) for a smart world. TENG has many advantages that make it suitable for a wide range of applications, including energy harvesting, environmental protection, wearable electronics, robotics, and self-powered sensors. Sensing as an important part of TENG applications is gradually expanding, with the in-depth study of TENG sensing in its working principle, material selection, processing technology, system integration, surface treatment, and back-end algorithms by researchers. In industry and academia, fluid dynamics sensing for liquid and air is urgently needed but lacking. In particular, local fluid sensing is difficult and limited to traditional sensors. Fortunately, with advantages for ordinary TENGs and TENGs as fluid dynamics sensors, fluid dynamics sensing can be better realized. Therefore, the paper summarizes the up-to-date work on TENGs as fluid dynamics sensors, discusses the advantages of TENGs as fluid dynamics sensors in-depth, and, most importantly, aims to explore possible new key areas to help guide the future direction of TENG in fluid dynamics sensing by addressing the key challenges.
RESUMO
Surface charge density (σSC) is essential to the output of the triboelectric nanogenerator (TENG). Massive efforts have been made to improve it, which can be totally categorized into four types. Two of them are utilized to optimize the basic electrification of the TENG, and the other two are for the device configuration and following circuits. However, the basic electrification of the 100 µm-thick film under ambient conditions still stays below 200 µC m-2. Herein, we proposed a brand-new technical route, by designing an asymmetric-internal-capacitance configuration, which forms a "hot surface" rich in free electrons at the electrification interface and finally promotes σSC to 550 µC m-2. Specifically, σSC of Cu is improved by 35 times, reaching 9.48 times that of nylon that is reported to be a strong positive triboelectric material. Furthermore, the hot surface improves the output of the TENG by 12.8 times and drives multiple devices floating in water to work stably, showing great potential in harvesting water wave energy (blue energy).
RESUMO
The release and dissolution of an active pharmaceutical ingredient (API) from the solid oral formulation into the gastrointestinal (GI) tract is critical for the drug's absorption into systemic circulation. Extended-release (ER) solid oral dosage forms are normally subjected to physical shear and grinding forces as well as pressure exerted by peristaltic movements when passing through the GI tract. The complex physical contraction and sample friction exerted by the GI tract are not simulated well by compendial dissolution methods. These limitations render traditional in vitro dissolution testing unable to discriminate and predict a product's in vivo performance. The objective of this study was to develop a dissolution method that better simulates the GI environment that products are subject to when taken by patients. A newly designed Mechanical Apparatus under GI Conditions (MAGIC) was assembled with a dissolution platform and mechanical capabilities to allow in vitro dissolution testing under sample contractions and friction. The dissolution platform, with medium flow-through configuration, was manufactured by 3D printing. A 60 mg polymer matrix-based ER nifedipine product was tested. To simulate GI physiological conditions during the dissolution testing, the flow rate of the medium, and a combination of mechanical compression with rotation induced sample friction at various rotation frequencies were explored. The polymer matrix-based nifedipine ER formulation used here failed its controlled release functionality in the simulated GI environment under mechanical compression and sample friction. The results showed that the MAGIC system, with flow-through configuration under compression and sample friction, has advantages over compendial methods in testing ER solid oral formulations.