Atmospheric dust deposition on soils around an abandoned fluorite mine (Hammam Zriba, NE Tunisia).

The present study focuses on the eolian dispersion and dust deposition, of major and trace elements in soils in a semi-arid climate, around an old fluorite (CaF2) and barite (BaSO4) mine, located in Hammam Zriba in Northern Tunisia. Ore deposits from this site contain a high amount of metal sulphides constituting heavy metal pollution in the surrounding environment. Samples of waste from the surface of mine tailings and agricultural topsoil samples in the vicinity of the mine were collected. The soil samples and a control sample from unpolluted area, were taken in the direction of prevailing northwest and west winds. Chemical analysis of these solids was performed using both X-ray fluorescence and X-ray diffraction. To determine the transfer from mine wastes to the soils, soluble fraction was performed by inductively coupled plasma and ionic chromatography. The fine grained size fraction of the un-restored tailings, still contained significant levels of barium, strontium, sulphur, fluorine, zinc and lead with mean percentages (wt%) of 30 (calculated as BaO), 13 (as SrO), 10 (as SO3), 4 (F), 2 (Zn) and 1.2 (Pb). Also, high concentrations of cadmium (Cd), arsenic (As) and mercury (Hg) were found with an averages of 36, 24 and 1.2mgkg-1, respectively. As a result of the eolian erosion of the tailings and their subsequent wind transport, the concentrations of Ba, Sr, S, F, Zn and Pb were extremely high in the soils near to the tailings dumps, with 5%, 4%, 7%, 1%, 0.8% and 0.2%, respectively. Concentration of major pollutants decreases with distance, but they were high even in the farthest samples. Same spatial distribution was observed for Cd, As and Hg. While, the other elements follow different spatial patterns. The leaching test revealed that most elements in the mining wastes, except for the anions, had a low solubility despite their high bulk concentrations. According the 2003/33/CE Decision Threshold, some of these tailings samples were considered as hazardous. Furthermore, other waste samples, considered non hazardous, were not inert. In contrast, the SO42-, Ba, Pb and Sb leachable contents measured in most of the soil samples were relatively high, exceeding the inert threshold for landfill disposal of wastes.

Evaluation of pollution by heavy metals of an abandoned Pb-Zn mine in northern Tunisia using sequential fractionation and geostatistical mapping.

This study investigates the contents of lead, zinc, and cadmium in 109 near-surface soil samples collected around the abandoned mine of Fedj Lahdoum, northern Tunisia, to assess the risk of pollution they generate. The study involved some analytical procedures such as pH measurements, X-ray diffraction techniques, sequential fractionation, and geostatistical mapping using the ordinary Kriging techniques. The sequential fractionation revealed that the bioavailability of Pb, Zn, and Cd follows the orders F5 > F3 ¼ F4 > F2 ¼ F1, F5 > F3 ¼ F4 ¼ F2 > F1 and F5 > F2 ¼ F4 > F1, respectively; their associations with organic matter and residual sulfides (F4) are relatively low. However, their high cumulated contents are dominantly associated with the residual (F5) and reducible (F3) fractions. The geostatistical mapping was endeavored to predict the spatial distribution of the studied heavy metals at unsampled sites and to produce a cumulated risk map of soil pollution. The latter is discussed with emphasis of the main factors responsible for the scattering of the pollution as much as the landscape conditions, the chemical composition of the mine tailings, the surface drainage of meteoric water and the wind. This study provides insight into the delineation of the spatial spreading of Pb, Zn, and Cd around the abandoned mine Fedj Lahdoum and their surrounding urban areas. It reveals that the mine infrastructure areas encompassing both extraction and processing and tailing deposition areas are the main sources of contamination. And the landscape conditions together with the surface drainage of meteoric water and the wind are the main factors responsible for the scattering of the pollution.