RESUMO
Traditional soil phosphorus (P) sorption capacity is examined from a Langmuir isotherm batch technique, which is time-consuming, labour intensive and generates chemical waste. In this work, we provide an efficient and convenient technique with MIR spectroscopy to predict the Langmuir parameter of soil P sorption maximum capacity (Smax, mg·kg-1). Four spectral libraries from benchtop (Bruker) and handheld (Agilent) MIR spectrometers were built with samples in two particle size ranges, <0.100 mm (ball-milled) and <2 mm. respectively. Using an archive of samples with a database of sorption parameters, soils were classified into 'low' and 'high' sorption capacities. Chemometric regression models of partial least squares (PLS), Cubist, support vector machine (SVM) regression and random forest (RF) were evaluated for Smax prediction. Bruker spectral libraries with both soil particle sizes yielded 'excellent models', with SVM predicting Smax values with high accuracy (RPIQV = 4.50 and 4.25 for the spectral libraries of the ball-milled and <2 mm samples, respectively). In comparison, the Agilent handheld spectral libraries contained more noise and less resolution. For Agilent MIR spectroscopy, more homogeneous samples after ball milling resulted in a higher accurate Smax prediction. For Agilent libraries of ball-milled samples, an 'approximate quantitative model' (RPIQV = 2.74) was obtained from the raw spectra using the Cubist algorithm. However, for Agilent spectroscopy of <2 mm samples, the best performing Cubist algorithm can only achieve a 'fair model' (RPIQV=2.23) with the potential to discriminate between 'low' and 'high' Smax values. The results suggest that the benchtop spectrometer can predict the Langmuir Smax value with high accuracy without the need to ball mill samples. However, the handheld spectrometer can only make approximate quantitative predictions of Smax for ball-milled samples. For <2 mm samples, Agilent can only be used to classify 'low' and 'high' sorption capacity soils.