Spin-singlet Quantum Ground State in Zigzag Spin Ladder Cu(CF3 COO)2.

The copper salt of trifluoroacetic acid, Cu(CF3 COO)2 , offers a new platform to investigate the quantum ground states of low-dimensional magnets. In practice, it realizes the ideal case of a solid hosting essentially isolated magnetic monolayers. These entities are constituted by well-separated two-leg half-integer spin ladders organized in a zigzag fashion. The ladders are comprised of dimeric units of edge-sharing tetragonal pyramids coupled through carbon ions. The spin-gap state in this compound was revealed by static and dynamic magnetic measurements. No indications of long range magnetic ordering down to liquid helium temperature were obtained in specific heat measurements. First principles calculations allow estimation of the main exchange interaction parameters, J⊥ =176 K and J∥ =12 K, consistent with the weakly interacting dimers model.

Ising-like Magnetism in Quasi-Two-Dimensional Co(NO3)2·2H2O.

The appearance of electrically neutral water molecules in the structure of cobalt dinitrate dihydrate, Co(NO3)2⋅2H2O, drastically changes its magnetic properties as compared to its waterless counterpart, Co(NO3)2. The title compound shows Ising-like behavior reflected in its thermodynamic properties. It experiences long-range antiferromagnetic order at TN = 20.5 K and metamagnetic transition at µ0HC = 0.76 T. First-principles calculations produce the values of leading exchange interactions J1 ~ 10 K and J2 ~ 0.5 K and single-ion anisotropy D ~ 1 K which allows us to consider Co(NO3)2⋅2H2O as a quasi-two-dimensional magnetic system.