Mobilisation of textile waste to recover high added value products and energy for the transition to circular economy.

The textile industry is a major contributor to global waste, with millions of tons of textiles being discarded annually. Material and energy recovery within circular economy offer sustainable solutions to this problem by extending the life cycle of textiles through repurposing, recycling, and upcycling. These initiatives not only reduce waste but also contribute to the reduction of the demand for virgin materials (i.e. cotton, wool), ultimately benefiting the environment and society. The circular economy approach, which aims to recreate environmental, economic, and societal value, is based on three key principles: waste reduction, material circulation, and ecological restoration. Given these difficulties, circularity incorporates the material recovery approach, which is focused on the conversion of waste into secondary raw resources. The goal of this notion is to extract more value from resources by prolonging final disposal as long as feasible. When a textile has outlived its functional life, material recovery is critical for returning the included materials or energy into the manufacturing cycle. The aim of this paper is to examine the material and energy recovery options of main raw materials used in the fashion industry while highlighting the need of close observation of the relation between circularity and material recovery, including the investigation of barriers to the transition towards a truly circular fashion industry. The final results refer to the main barriers of circular economy transition within the industry and a framework is proposed. These insights are useful for academia, engineers, policy makers and other key stakeholders for the clear understanding of the industry from within and highlight beyond circular economy targets, SDGs interactions with energy and material recovery of textile waste (SDG 7, SDG 11, SDG 12 etc.).

100 kW peak power external cavity diamond Raman laser at 2.52 µm.

We report an external cavity diamond Raman laser operating at 2.52 µm, pumped by a 1.89 µm Tm:LiYF4 (YLF) laser. The maximum pulse energy at 2.52 µm is 1.67 mJ for 4.4 mJ of pump, yielding a conversion efficiency of 38%. The best slope efficiency is ~60% and the Raman pulse duration is between 11 and 15 ns for ~33 ns pump pulse duration. The peak power at 2.52 µm is >100 kW. This demonstration of a Thulium laser pumped diamond Raman laser paves the way for accessing the industrially important wavelength region of ~2.5 µm.

Nonlinear refractive index of ultrafast laser inscribed waveguides in gallium lanthanum sulphide.

We demonstrate ultrafast all-optical switching in femtosecond laser inscribed nonlinear directional couplers in gallium lanthanum sulphide operated at 1.55 µm. We report on the evaluation of the nonlinear refractive index of the waveguides forming the directional couplers by making use of the switching parameters. The nonlinear refractive index is reduced by the inscription process to about 4-5 times compared to bulk material.

Nonlinear optical properties of multilayer graphene in the infrared.

A negative value for the nonlinear refraction in graphene is experimentally observed and unambiguously verified by performing a theoretical analysis arising from the conductivity of the graphene monolayer. The nonlinear optical properties of multi-layer graphene are experimentally studied by employing the Z-scan technique. The measurements are carried out at 1150, 1550, 1900 and 2400 nm with a 100-femtosecond laser source. Under laser illumination the multi-layer graphene exhibits a transmittance increase due to saturable absorption, followed by optical limiting due to two-photon absorption. The saturation irradiance Isat and the two-photon absorption coefficient ß are measured in the operating wavelength range. Furthermore, an irradiance-dependent nonlinear refraction is observed and discriminated from the conventional nonlinear refraction coefficient n2, which is not irradiance dependent. The values obtained for the irradiance-dependent nonlinear refraction are in the order of ∼10-9 cm2W-1, approximately 8 orders of magnitude larger than any bulk dielectrics.

Refractive index and dispersion control of ultrafast laser inscribed waveguides in gallium lanthanum sulphide for near and mid-infrared applications.

The powerful ultrafast laser inscription technique is used to fabricate optical waveguides in gallium lanthanum sulphide substrates. For the first time the refractive index profile and the dispersion of such ultrafast laser inscribed waveguides are experimentally measured. In addition the Zero Dispersion Wavelength of both the waveguides and bulk substrate is experimentally determined. The Zero Dispersion Wavelength was determined to be between 3.66 and 3.71 µm for the waveguides and about 3.61 µm for the bulk. This work paves the way for realizing ultrafast laser inscribed waveguide devices in gallium lanthanum sulphide glasses for near and mid-IR applications.