Binary homogeneous nucleation in water-succinic acid and water-glutaric acid systems.

Binary homogeneous nucleation of water-succinic acid and water-glutaric acid systems have been investigated. The numerical approach was based on the classical nucleation theory. Usually, nucleation is discussed in terms of kinetics, but the thermodynamics involved is undoubtedly equally important. In this paper we studied the above mentioned binary systems giving a quantitative insight into the nucleation process and a detailed consideration of the thermodynamics involved. Both diacids in study are in solid state at room temperature. They behave in environment according to their liquid state properties because of the absence of crystalline lattice energies, and therefore their subcooled liquid state thermodynamics have to be considered. The lack of consistent thermodynamic data for pure organic components and their aqueous solutions represent a high source of uncertainty. However, the present simulations indicate that in atmospheric conditions these binary systems will not form new particles.

Particle concentration profile in a vertical displacement flow: a study in an industrial hall.

The effect of displacement flow on the distribution of aerosol concentration was investigated in an industrial hall. According to the displacement ventilation principle, vertical upflow is accomplished by introducing fresh air, cooler than room air, into the occupied zone near floor level. The fresh air is introduced from low-velocity devices and heated by warm processes. This technique allows warm air contaminants to rise to the ceiling, and the rising plume is then exhausted close to the ceiling. This study presents the results of a field study conducted in an industrial environment. The aerosol properties and behavior, especially the vertical gradients, are characterized in a displacement flow field. The results indicate that the fine particles, less than 1 microm in diameter, are transported away from the breathing zone by the ventilation process. However, the air quality is significantly influenced by the emission source, and therefore the number concentration of fine and ultrafine (smaller than 0.1 microm in diameter) aerosol particles in the breathing zone was clearly elevated compared to that of the incoming clean air. The vertical gradients displayed clear size dependence; the strongest gradients were found for particles between 0.003 and 0.015 microm in diameter.