New open burning policy reshaped the aerosol characteristics of agricultural fire episodes in Northeast China.

The massive agricultural sector in the Northeast Plain, which is of great importance for the food security in China, results in a huge amount of crop residues and thus substantial concern on haze pollution due to biomass burning (BB). To seek for effective control measures on BB emissions, a dramatic transition of open burning policy occurred in Heilongjiang Province, from the "legitimate burning" policy released in 2018 to the "strict prohibition" policy implemented in 2019 and beyond. Here we explored the BB aerosols during 2020-2021 in Harbin, the capital city of Heilongjiang. Although open burning was strictly prohibited by mandatory bans, agricultural fires were not actually eliminated, as indicated by the levoglucosan levels and fire count results. In general, the BB aerosols in Harbin were attributed to the overlaying of household burning and agricultural fire emissions. The former factor laid the foundation of biomass burning impacts, with BB contributions to organic carbon and elemental carbon (fBBOC and fBBEC) of 35 and 47%, respectively. The latter further enhanced the BB impacts during specific episodes breaking out in the spring of 2021 as well as the fall of 2020, when fBBOC and fBBEC increased to 64 and 57%, respectively. In addition, comparing to the fires of 2018-2019 which occurred in winter (in response to the "legitimate burning" policy), the agricultural fires were shifted to spring and fall in the 2020-2021 campaign, accompanied with an increase of combustion efficiency. This study illustrated how the agricultural fire emissions were influenced by the transition of open burning policy.

Strong biomass burning contribution to ambient aerosol during heating season in a megacity in Northeast China: Effectiveness of agricultural fire bans?

Sustainable use of crop residues remains a challenge in main agricultural regions of China such as the Northeast Plain. Here we investigated the impacts of biomass burning on fine particle (PM2.5) during a six-month long heating season in the Harbin-Changchun (HC) metropolitan area, China's only national-level city cluster located in the severe cold climate region. Temporal variation of PM2.5 was found to coincide with that of levoglucosan. This was attributed to the strong contribution of biomass burning to organic aerosol (the dominant component in PM2.5), as supported by the source apportionment results and high levoglucosan-to-organic carbon (OC) ratios. Furthermore, the variation of biomass burning contribution was inferred to be driven mainly by agricultural fires with relatively low combustion efficiencies, based on a synthesis of the relationship between OC and elemental carbon (EC), the dependence of EC on carbon monoxide, and the relative abundances of different tracers for biomass burning. Nitrate formation was enhanced during biomass burning episodes whereas no evidence was observed to indicate enhanced sulfate formation or net increase of OC mass due to secondary formation. This study demonstrates the importance of open burning as a source of haze pollution in the HC region.

Secondary inorganic aerosol during heating season in a megacity in Northeast China: Evidence for heterogeneous chemistry in severe cold climate region.

The characteristics of secondary inorganic aerosol including sulfate, nitrate and ammonium (SNA) were investigated during a six-month long heating season in the Harbin-Changchun metropolitan area, i.e., China's only national-level city cluster located in the severe cold climate region. The contribution of SNA to fine particulate matter (PM2.5) tended to decrease with increasing PM2.5 concentration, opposite to the trend repeatedly observed during winter in Beijing. Heterogeneous sulfate formation was still evident when the daily average temperature was as low as below -10 °C, with the preconditions of high relative humidity (RH; above ∼80%) and high nitrogen dioxide (above ∼60 µg/m3). Both the sulfur oxidation ratio (SOR) and nitrogen oxidation ratio (NOR) were enhanced at high RH, reaching ∼0.3. However, the high RH conditions were not commonly seen during the heating season, which should be responsible for the overall lack of linkage between the SNA contribution and PM2.5 temporal variation.

[Patterns of Mortality from Air Pollutant Emissions in China's Coal-fired Power Plants].

Based on the high-resolution coal-fired power plant emission database, GEOS-Chem Adjoint, a global-regional nested atmospheric chemistry model and its adjoint were applied to analyze PM2.5-related premature deaths caused by the power sector in six grid regions of China due to air pollutant emissions and subsequent pollution. The results show that power sector-related PM2.5 pollution caused 106000 (95% CI:68000-132000) premature deaths in 2010, accounting for 9.8% of China's anthropogenic PM2.5-related premature deaths. The health loss intensity (defined as number of premature deaths caused by a unit of power generation) of small and old units is significantly higher than that of large and new units:units with a capacity below 100 MW reach 62 people·(TW·h)-1, 2.8 times that of units with a capacity above 600 MW. Similarly, the health loss intensity of units older than thirty years is 58 people·(TW·h)-1, 2.1 times that of new units. From the perspective of regional grids, the health impact index of Central China is relatively large, reaching 77 people·(TW·h)-1. Further analysis reveals that transregional power transmission led to a net increase of 680 premature deaths compared with the scenario without transmission in 2010. Our study implies that China should accelerate the pace of phasing out small and old units and optimize the power transmission distribution between grid regions to reduce the overall level of pollution and health losses.