1.
Chem Commun (Camb)
; 51(70): 13527-30, 2015 Sep 11.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26219388
RESUMO
The first π-coordination-catalyzed nucleophilic fluorination of unactivated aryl halides has been demonstrated. Chlorobenzene reacts with alkali metal fluorides (CsF, KF) in the presence of a Cp*Ru catalyst at 120-180 °C to give fluorobenzene.