Recent advances in instrumental techniques for heavy metal quantification.

Heavy metals (HMs) are ubiquitous; they are found in soil, water, air, and all biological matrices. The toxicity, bioaccumulation potential, and deleterious effects of most of these metals on humans and the environment have been widely documented. Consequently, the detection and quantification of HMs in various environmental samples have become a pressing issue. The analysis of the concentrations of HMs is a vital component of environmental monitoring; hence, the selection of the most suitable analytical technique for their determination has become a topic of great interest in food, environment, and human health safety. Analytical techniques for the quantification of these metals have evolved. Presently, a broad range of HM analytical techniques are available with each having its outstanding merits as well as limitations. Most analytical scientists, therefore, adopt complementation of more than one method, with the choice influenced by the specific metal of interest, desired limits of detection and quantification, nature of the interference, level of sensitivity, and precision among others. Sequel to the above, this work comprehensively reviews the most recent advances in instrumental techniques for the determination of HMs. It gives a general overview of the concept of HMs, their sources, and why their accurate quantification is pertinent. It highlights various conventional and more advanced techniques for HM determination, and as one of its kind, it also gives special attention to the specific merits and demerits of the analytical techniques. Finally, it presents the most recent studies in this regard.

Chemometric approach in environmental pollution analysis: A critical review.

With the ever-increasing global population and industrialization, it has become a call of the hour to start taking care of the environment to balance the ecosystem. For this, effective monitoring and assessment are required, which involves collecting and measuring environmental details, temporal and spatial readings of environmental data, and parameters. However, assessment of the environment is very tedious as it includes monitoring target analytes, identifying their sources, and reporting, which invariably implies that detailed environmental monitoring would be an intricate and expensive process. The traditional protocols in environmental measures are often manual and time demanding, which makes it further difficult. Moreover, several changes also occur within the environment, which could be chemical, physical, or biological, and since these environmental impacts are often cumulative, it becomes difficult to measure an isolated system. Furthermore, the chances of skipping significant results and trends become high. Also, experimental data obtained from the environmental analysis are usually non-linear and multi-variant due to different associations among various contributing variables. Therefore, it is implied that accurate measurements and environment monitoring are not using traditional analytical protocols. Thus, the need for a chemometric approach in environmental pollution analysis becomes paramount due to the inherent limitations associated with the conventional approach of analyzing environmental datasets. Chemometrics has appeared as a potential technique, which enhances the particulars of the chemical datasets by using statistical and mathematical analysis methods to analyze chemical data beyond univariate analysis. Utilizing chemometrics to study the environmental data is a revolutionary idea as it helps identify the relationship between sources of contaminations, environmental drivers, and their impact on the environment. Hence, this review critically explores the concept of chemometrics and its application in environmental pollution analysis by briefly highlighting the idea of chemometrics, its types, applications, advantages, and limitations in the environmental domain. An attempt is also made to present future trends in applications of chemometrics in environmental pollution analysis.

Recent advances in nanotechnology for remediation of heavy metals.

Heavy metal contamination of the environment has become an alarming environmental issue that has constituted serious threats to humans and the ecosystem. These metals have been identified as a priority class of pollutants due to their persistency in the environment and their potential to bioaccumulate in biological systems. Consequently, the remediation of heavy metals from various environmental matrices becomes a critical topic from the biological and environmental perspectives. To this end, various research interests have shifted to the need to put forward economically feasible and highly efficient approaches for mitigating these contaminants in the environment. Thus, numerous conventional approaches have reportedly been employed for the remediation of heavy metals, with each of the methods having its inherent limitations. More recently, studies have revealed that nanomaterials in their various forms show unique potential for the removal of various contaminants including heavy metals in comparison to their bulk counterparts making them a topic of importance to researchers in various fields. Also, various studies have documented specifically tailored nanomaterials that have been synthesized for the removal of heavy metals from various environmental matrices. This review provides up-to-date information on the application of nanotechnology for the remediation of heavy metals. It highlights various nanomaterials that have been employed for the remediation of heavy metals, current details on their methods of synthesis, factors affecting their adsorption processes, and the environmental and health impact of nanomaterials. Finally, it provides the challenges and future trends of nanomaterials for heavy metal removal.