Assessment of new functional units for agrivoltaic systems.

In agrivoltaic systems, photovoltaic (PV) modules are ground-mounted between crops replacing a part of greenhouse or are set below or above the cover film of greenhouse; these can provide solutions with respect to land competition and climate change mitigation. These systems have certain additional functions, namely, sunlight sharing, land sharing and power generation, as compared to the conventional agricultural production systems. These new functions are not adequately performed by traditionally used functional units (FUs), such as the mass- or the area-based FU, in agricultural life cycle assessment (LCA). Therefore, this study proposed new FUs for agrivoltaic systems, namely the modified area-based FU and the monetary-based FU. The modified area-based FU was derived by adding area covered by PV modules to the cultivated area addressing the function of land sharing. The monetary-based FU was derived by adding the prices of crops and electricity addressing the function of the system as a producer of differently valued market goods. The traditional area-based FU is based on the function of solar sharing because crop cultivation and power generation share the same sunlight falling on the same land. These new and traditional FUs were applied to a tomato greenhouse, with and without organic photovoltaics, as a case study of Japan. A combination of traditional and new FUs helps to maintain focus on crop production as the primary function of agricultural land and to better understand the environmental impacts of agrivoltaic systems. Finally, as the sharing of sunlight and land happen simultaneously, a method that addresses both these functions while reporting LCA results was considered.

The Effect of Polyvinyl Alcohol Addition on the Optical Properties and Oxygen Detection Performance of Titanium Dioxide and Methylene Blue Nanocomposite Colorimetric Indicators.

In this study, we investigated the impact of polyvinyl alcohol (PVA) incorporation on the optical properties and oxygen detection performance of a titanium dioxide/methylene blue (TiO2/MB) nanocomposite colorimetric indicator for packaging applications. The nanocomposite was synthesized via mechanical milling of TiO2 nanoparticles with MB and citric acid. PVA, at varying concentrations (0, 3, 9, and 14 wt%), was introduced during the wet milling process to produce a homogeneous composite film. Spin coating was employed to fabricate TiO2/MB nanocomposite films for oxygen detection evaluation. The influence of PVA loading on the films' chemical functionalities and surface morphologies was assessed using Fourier-transform infrared spectroscopy (FTIR) and field-emission scanning electron microscopy (FE-SEM). The indicator's activation process, involving a color change between bleached and colored states, and its recovery time were monitored via optical imaging and UV-VIS-NIR spectrophotometry. The results revealed that a PVA content of 9 wt% yielded well-defined films with enhanced stability of the TiO2/MB nanocomposite's oxygen detection performance.

Scientific justifications for the political decision-making on environmental remediation carried out after the Fukushima nuclear accident.

The Japanese government decided to implement environmental remediation after the Fukushima Daiichi Nuclear Power Plant (termed "1F" in Japan) accident on 11th March 2011. As the initial additional annual dose target was set to be 1 mSv or less as a long-term goal, we examined the decision-making process undertaken by the then leaders, particularly the Minister of the Ministry of the Environment (MOE) who was responsible for the final decision. We found that technically based assessment of dose targets, health effects and risk-based approaches justified by scientific experts were not communicated to the then Minister and officials of the MOE before the remediation strategy was decided. We defined how such a decision was made based on leadership theories such as the Role Theory and the Cognitive Resources Theory. Academic leaders could have examined the Windscale accident (UK, 1957), which could be considered as the closest analogue (at least in terms of radionuclide releases) to the 1F accident. Environmental remediation could have been planned and implemented more effectively whilst still maintaining the highest possible safety standards and balancing the environmental and economic burden. Appropriate scientific input should have been provided by academic leaders to political and administrative leaders and such scientific justification should have been disclosed to the general public (especially the residents of Fukushima Prefecture) so that the general public could have developed greater trust in their leaders and have more readily accepted the decisions made.

Discovery of Amorphous Iron Hydrides via Novel Quiescent Reaction in Aqueous Solution.

Novel amorphous iron hydrides (AIHs) are synthesized for the first time under ambient conditions by employing novel "quiescent reaction", without stirring for mixing solutions, during a conventional aqueous reduction-precipitation process. The kind and morphology of AIHs are dependent on the processing condition, where two types are found, with one form consisting of a tangle of uniform nanowires and the other being granular in nature. Both AIHs undergo transformation to crystalline α-Fe by heat treatment at 600 °C. The nanowire AIH exhibits the hydrogen content of 0.10 wt%, while the granular AIH of 0.22 wt%. Their magnetic and thermal properties are accordingly different, and the non-diffusive hydrogen contributes to stability of AIHs. It is strongly suggested that, by use of quiescent reaction, iron-hydrogen clusters are formed and preserved at an early stage of precipitation reaction, and subsequently aggregated into novel AIHs, preventing α-Fe crystallization. Hence, the AIHs would be categorized as metastable hydrides stabilized with iron-hydrogen clusters. In addition, newly discovered quiescent reaction in aqueous solution, from which unprecedented AIHs are derived, sheds new light on fundamental and essential aqueous reaction.

Structure and catalytic behaviour of CuO-CeO2 prepared by high-energy ball milling.

The aim of this study is to prepare CuO-CeO2 composite by means of mechanical milling and to investigate its characteristics as a catalyst. The structural and morphological features of milled samples are observed by X-ray diffractometry and scanning electron microscopy. The redox property and total OSC (oxygen storage capacity) of the milled sample were measured by using GC-TCD and TG-DTA, which are important parameters to indicate the effectiveness of catalysts. Interestingly, reduction of CuO is repeatedly observed when milling of CuO-CeO2 powder mixture is processed in air. The redox property of milled CuO-CeO2 sample is investigated by H2-TPR, where three reduction peaks are observed for 0 h milling and only one broad peak for various other milling times. The total OSC of mechanically driven CuO-CeO2 catalyst is much higher than that of the CeO2-ZrO2 traditional catalyst system at low temperatures.

An optimum treatment for waste electronic home appliance in remote area: The case of Kinmen, Taiwan.

An optimum treatment system for the waste electronic home appliance in remote area by local pre-processing and outsourcing post-processing is proposed. The cost reduction potential of the proposed treatment system is presented for main four types of electronic home appliances by the case study of Kinmen, Taiwan. Implementation of local pre-processing in Kinmen, Taiwan can provide 42, 54, 32, and 41 TWD unit cost reduction for television, washing machine, refrigerator, and air conditioner, respectively, comparing to the current treatment system. The different treatment characteristics according to the type of the appliances are the major factors for the applicability and cost reduction potential of the local pre-processing system. The application of this system to other cases is presented by sensitivity analysis with relative labor cost and transportation distance as the parameters. The results and the analysis process can be applied to the domestic systems with regions without recycling facilities, and also the international systems under the extended producer responsibility concept to take back the products for recycling.

New LnOCl (Ln = Sm, Nd) photocatalyst and novel cocatalytic effect on BiOCl in humid environment.

This is the first report on photocatalytic properties of LnOCl (Ln = Sm, Nd) compounds, and the novel cocatalytic effect on BiOCl in highly humid environments, evaluated via the photoremoval of nitric oxide (NO).

Gushing in canned beer: the effect of ultrasonic vibration.

Everybody has had the experience of a canned carbonated drink overflowing and soiling their clothes. It is difficult to guess the amount of overflow before opening the can, although the phenomenon can be simply explained as the result of the formation of gas bubbles. In this article, we report the surprising result that intensive shaking using ultrasonic vibration can calm this effect in beer. These experiments showed evidence of a memory effect in liquid. The 'calming down' is due to a fine balancing act between a change in the amount of microbubbles (or embryos) and a change in the pattern of their size distribution. Our experimental evidence shows that modification of the pre-existing microbubbles noticeably influences the subsequent nucleation, and this may open a new route to nucleation studies.