1.
Chem Commun (Camb)
; 46(42): 7915-7, 2010 Nov 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-20856982
RESUMO
The ruthenium hydride of (Ar(4)CpOH)Ru(CO)(2)H exchanges cleanly and rapidly with D(2) at room temperature to generate the ruthenium deuteride. A chain mechanism is proposed to explain the much more rapid exchange of RuH/D(2) than RuCO exchange with (13)CO.