Optimized MBR for greywater reuse systems in hotel facilities.

Greywater is an important alternative water source, particularly in semi-arid, touristic areas, where the biggest water demand is usually in the dry period. By using this source wisely, tourist facilities can substantially reduce the pressure to scarce water resources. In densely urbanized touristic areas, where space has high value, compact solutions such as MBR based greywater reuse systems appear very appropriate. This research focuses on technical and economical evaluation of such solution by implementing a pilot MBR to a hotel with separated grey water. The pilot was operated for 6 months, with thorough characterisation of the GW performed, its operation was monitored and its energy consumption was optimized by applying a control system for the air scour. Based on the pilot operation a design and economic model was set to estimate the feasibility (CAPEX, OPEX, payback period of investment) of appropriate scales of MBR based GW systems, including separation of GW, MBR technology, clean water storage and disinfection. The model takes into account water and energy prices in Spain and a planning period of 20 years. The results demonstrated an excellent performance in terms of effluent quality, while the energy demand for air-scour was reduced by up to 35.2%, compared to the manufacturer recommendations. Economical evaluation of the entire MBR based GW reuse system shows its feasibility for sizes already at 5 m3/day (60 PE). The payback period of the investment for hotels like the demonstration hotel, treating 30 m3/day is 3 years.

Cost comparison of full-scale water reclamation technologies with an emphasis on membrane bioreactors.

The paper assesses the costs of full-scale membrane bioreactors (MBRs). Capital expenditures (CAPEX) and operating expenses (OPEX) of Spanish MBR facilities have been verified and compared to activated sludge plants (CAS) using water reclamation treatment (both conventional and advanced). Spanish MBR facilities require a production of 0.6 to 1.2 kWh per m3, while extended aeration (EA) and advanced reclamation treatment require 1.2 kWh per m3. The energy represents around 40% of the OPEX in MBRs. In terms of CAPEX, the implementation costs of a CAS facility followed by conventional water reclamation treatment (physical-chemical + sand filtration + disinfection) ranged from 730 to 850 €.m-3d, and from 1,050 to 1,250 €.m-3d in the case of advanced reclamation treatment facilities (membrane filtration) with a capacity of 8,000 to 15,000 m3d-1. The MBR cost for similar capacities ranges between 700 and 960 €.m-3d. This study shows that MBRs that have been recently installed represent a cost competitive option for water reuse applications for medium and large capacities (over 10,000 m3d-1), with similar OPEX to EA and conventional water reclamation treatment. In terms of CAPEX, MBRs are cheaper than EA, followed by advanced water reclamation treatment.

Model-based methodology for the design of optimal control strategies in MBR plants.

This paper proposes a model-based methodology that allows synthesising the most appropriate strategies for optimising the operation of wastewater treatment plants (WWTPs). The methodology is applied with the aim of maximising the nitrogen removal in membrane bioreactors (MBRs). The proposed procedure is based on a systematic approach composed of four steps. First, a sensitivity analysis of the input variables is carried out in order to obtain a first assessment of the potential for operational improvements. Then, the optimum input variable values are calculated by a model-based optimisation algorithm that minimises a cost function associated with the effluent total nitrogen at different temperatures. Then, the optimum operational strategies are identified. Finally, these operational strategies form the conceptual knowledge base for designing automatic control laws. The obtained optimal control strategies have shown a significant improvement in performance in comparison with fixed operation for the studied case, reducing the total nitrogen by 40%.

Proteomics reliability for micropollutants degradation insight into activated sludge systems.

Little information is available on pharmaceutical trace compounds degradation pathways in wastewater. The potential of the proteomics approach has been evaluated to extract information on activated sludge microbial metabolism in degrading a trace concentration of a pharmaceutical compound (ibuprofen). Ibuprofen is one of the most consumed pharmaceuticals, measured in wastewater at very high concentrations and, despite its high removal rates, found in different environmental compartments. Aerated and completely mixed activated sludge batch tests were spiked with ibuprofen at 10 and 1,000 µg L(-1). Ibuprofen concentrations were determined in the liquid phase: 100% removal was observed and the kinetics were estimated. The solid phase was sampled for proteomics purposes. The first objective was to apply proteomics to evaluate protein profile variations in a complex matrix such as activated sludge. The second objective was to determine, at different ibuprofen concentrations, which proteins followed pre-defined trends. No newly expressed proteins were found. Nonetheless, the obtained results suggest that proteomics itself is a promising methodology to be applied in this field. Statistical and comparative studies analyses provided, in fact, useful information on biological reproducibility and permitted us to detect 62 proteins following coherent and plausible expected trends in terms of presence and intensity change.

Impact of Integration of FO Membranes into a Granular Biomass AnMBR for Water Reuse.

The granular sludge based anaerobic membrane bioreactor (G-AnMBR) has gained emphasis in the last decade by combining AnMBR advantages (high quality permeate and biogas production towards energy positive treatment) and benefits of granular biomass (boosted biological activity and reduced membrane fouling). With the aim to further reduce energy costs, produce higher quality effluent for water reuse applications and improve system efficiency, a forward osmosis (FO) system was integrated into a 17 L G-AnMBR pilot. Plate and frame microfiltration modules were step by step replaced by submerged FO ones, synthetic wastewater was used as feed (chemical oxygen demand (COD) content 500 mg/L), with hydraulic retention time of 10 h and operated at 25 °C. The system was fed with granular biomass and after the acclimation period, operated neither with gas sparging nor relaxation at around 5 L.m-2.h-1 permeation flux during at least 10 days for each tested configuration. Process stability, impact of salinity on biomass, the produced water quality and organic matter removal efficiency were assessed and compared for the system working with 100% microfiltration (MF), 70% MF/30% FO, 50% MF/50% FO and 10% MF/90% FO, respectively. Increasing the FO share in the reactor led to salinity increase and to enhanced fouling propensity probably due to salinity shock on the active biomass, releasing extracellular polymeric substances (EPS) in the mixed liquor. However, above 90% COD degradation was observed for all configurations with a remaining COD content below 50 mg/L and below the detection limit for MF and FO permeates, respectively. FO membranes also proved to be less prone to fouling in comparison with MF ones. Complete salt mass balance demonstrated that major salinity increase in the reactor was due to reverse salt passage from the draw solution but also that salts from the feed solution could migrate to the draw solution. While FO membranes allow for full rejection and very high permeate purity, operation of G-AnMBR with FO membranes only is not recommended since MF presence acts as a purge and allows for reactor salinity stabilization.

Biological processes modelling for MBR systems: A review of the state-of-the-art focusing on SMP and EPS.

A mathematical correlation between biomass kinetic and membrane fouling can improve the understanding and spread of Membrane Bioreactor (MBR) technology, especially in solving the membrane fouling issues. On this behalf, this paper, produced by the International Water Association (IWA) Task Group on Membrane modelling and control, reviews the current state-of-the-art regarding the modelling of kinetic processes of biomass, focusing on modelling production and utilization of soluble microbial products (SMP) and extracellular polymeric substances (EPS). The key findings of this work show that the new conceptual approaches focus on the role of different bacterial groups in the formation and degradation of SMP/EPS. Even though several studies have been published regarding SMP modelling, there still needs to be more information due to the highly complicated SMP nature to facilitate the accurate modelling of membrane fouling. The EPS group has seldom been addressed in the literature, probably due to the knowledge deficiency concerning the triggers for production and degradation pathways in MBR systems, which require further efforts. Finally, the successful model applications showed that proper estimation of SMP and EPS by modelling approaches could optimise membrane fouling, which can influence the MBR energy consumption, operating costs, and greenhouse gas emissions.

Landfill Leachate Treatment by Using Second-Hand Reverse Osmosis Membranes: Long-Term Case Study in a Full-Scale Operating Facility.

Landfill leachate (LFL) has a complex inorganic, organic and microbiological composition. Although pressure-driven membrane technology contributes to reaching the discharge limits, the need for frequent membrane replacement (typically every 1-3 years) is an economical and environmental limitation. The goal of this work is to evaluate the feasibility of using second-hand reverse osmosis (RO) membranes to treat LFL in an industrially relevant environment. End-of-life RO membranes discarded from a seawater desalination plant were first tested with brackish water and directly reused or regenerated to fit with requirements for LFL treatment. A laboratory scale test of second-hand membrane reuse was carried out using ultrafiltered LFL. Then, a long-term test in an LFL full-scale facility was performed, where half of the membranes of the facility were replaced. The industrial plant was operated for 27 months with second-hand membranes. The permeate water quality fit the required standards and the process showed a trend of lower energy requirement (up to 12 bar lower transmembrane pressure and up to 9% higher recovery than the average of the previous 4 years). Direct reuse and membrane regeneration were successfully proven to be an alternative management to landfill disposal, boosting membranes towards the circular economy.

Climate change impact on EU rivers' dilution capacity and ecological status.

Impacts from urban wastewater treatment plants (WWTP) to receiving riverine surface water bodies (SWBs) depend on the load of contaminants discharged, as well as on their dilution capacity. Yet, climate change impacts on such dilution capacity and ultimately on the SWBs ecological status remain unclear. Here, we assess SWBs dilution capacity across the European continent to identify most vulnerable areas using information from centralized European databases. SWBs´ future dilution factor values are estimated based on representative concentration pathway scenarios impacts on rivers flow, and likely changes in European SWBs´ ecological status foretold. Results show that dilution factor in Europe increases by 5.4% in average. Yet, climate change effects are found to lead to a consistent dilution factor decrease for 11% of the 40074 European SWBs receiving WWTP discharge for the early century. This share reaches 17% for the midcentury period. We estimate that up to 42% of the SWBs receiving WWTP discharges and currently reaching a good ecological status show a 0.7 probability to have their ecological status downgraded due to climate change. Sites more vulnerable are located in the Mediterranean countries. Our findings highlight that climate change mitigation is essential for maintaining good ecological status in European SWBs.

Integrated membrane bioreactors modelling: A review on new comprehensive modelling framework.

Integrated Membrane Bioreactor (MBR) models, combination of biological and physical models, have been representing powerful tools for the accomplishment of high environmental sustainability. This paper, produced by the International Water Association (IWA) Task Group on Membrane Modelling and Control, reviews the state-of-the-art, identifying gaps for future researches, and proposes a new integrated MBR modelling framework. In particular, the framework aims to guide researchers and managers in pursuing good performances of MBRs in terms of effluent quality, operating costs (such as membrane fouling, energy consumption due to aeration) and mitigation of greenhouse gas emissions.

Selecting the most relevant variables for anaerobic digestion imbalances: two case studies.

In this study, a wrapper approach was applied to objectively select the most important variables related to two different anaerobic digestion imbalances, acidogenic states and foaming. This feature selection method, implemented in artificial neural networks (ANN), was performed using input and output data from a fully instrumented pilot plant (1 m3 upflow fixed bed digester). Results for acidogenic states showed that pH, volatile fatty acids, and inflow rate were the most relevant variables. Results for foaming showed that inflow rate and total organic carbon were among the relevant variables, both of which were related to the feed loading of the digester. Because there is not a complete agreement on the causes of foaming, these results highlight the role of digester feeding patterns in the development of foaming.

Multiple-objective evaluation of wastewater treatment plant control alternatives.

Besides the evaluation of the environmental issues, the correct assessment of wastewater treatment plants (WWTP) should take into account several objectives such as: economic e.g. operation costs; technical e.g. risk of suffering microbiology-related TSS separation problems; or legal e.g. accomplishment with the effluent standards in terms of the different pollution loads. For this reason, the main objective of this paper is to show the benefits of complementing the environmental assessment carried out by life cycle assessment with economical, technical and legal criteria. Using a preliminary version of the BSM2 as a case study, different combinations of controllers are implemented, simulated and evaluated. In the following step, the resulting multi-criteria matrix is mined using multivariate statistical techniques. The results showed that the presence of an external carbon source addition, the type of aeration system and the TSS controller are the key elements creating the differences amongst the alternatives. Also, it was possible to characterize the different control strategies according to a set of aggregated criteria. Additionally, the existing synergies amongst different objectives and their consequent trade-offs were identified. Finally, it was discovered that from the initial extensive list of evaluation criteria, only a small set of five are really discriminant, being useful to differentiate within the generated alternatives.

Fouling propensity of novel TFC membranes with different osmotic and hydraulic pressure driving forces.

The feasibility of Forward Osmosis (FO) as an alternative treatment technology to current membrane processes is believed to hinge on its reported lower fouling propensity. In this study, the impacts of constant osmotic pressure and hydraulic pressure driving forces on membrane fouling were investigated using a novel approach. In each case the cake layer was modelled accounting for all concentration polarisation effects and effective driving force. Compared to the widely employed method of using a non-constant osmotic pressure difference during bench-scale fouling experiments, maintaining a constant osmotic pressure led to 50% more alginate deposited on the same membrane surface (from 13.7 to 21.7 g/m2). This was attributed to a stronger osmotic driving force at the active layer interface and enhanced fouling due to a greater reverse flux of Na+ ions. An applied hydraulic pressure of 1 bar already changed fouling cake deposition and the cake structural parameter shrunk by 224 and 83 µm for the two thin-film composite membranes tested. A detailed analysis of the model however demonstrated that it needs further development, incorporating pore size, porosity and tortuosity of the foulant cake to enable drawing reliable conclusions on the causality of cake layer compaction.

Uncertainty and sensitivity analysis of control strategies using the benchmark simulation model No1 (BSM1).

The objective of this paper is to perform an uncertainty and sensitivity analysis of the predictions of the Benchmark Simulation Model (BSM) No. 1, when comparing four activated sludge control strategies. The Monte Carlo simulation technique is used to evaluate the uncertainty in the BSM1 predictions, considering the ASM1 bio-kinetic parameters and influent fractions as input uncertainties while the Effluent Quality Index (EQI) and the Operating Cost Index (OCI) are focused on as model outputs. The resulting Monte Carlo simulations are presented using descriptive statistics indicating the degree of uncertainty in the predicted EQI and OCI. Next, the Standard Regression Coefficients (SRC) method is used for sensitivity analysis to identify which input parameters influence the uncertainty in the EQI predictions the most. The results show that control strategies including an ammonium (S(NH)) controller reduce uncertainty in both overall pollution removal and effluent total Kjeldahl nitrogen. Also, control strategies with an external carbon source reduce the effluent nitrate (S(NO)) uncertainty increasing both their economical cost and variability as a trade-off. Finally, the maximum specific autotrophic growth rate (micro(A)) causes most of the variance in the effluent for all the evaluated control strategies. The influence of denitrification related parameters, e.g. eta(g) (anoxic growth rate correction factor) and eta(h) (anoxic hydrolysis rate correction factor), becomes less important when a S(NO) controller manipulating an external carbon source addition is implemented.

Evaluation of plant-wide WWTP control strategies including the effects of filamentous bulking sludge.

The main objective of this paper is to evaluate the effect of filamentous bulking sludge on the predicted performance of simulated plant-wide WWTP control strategies. First, as a reference case, several control strategies are implemented, simulated and evaluated using the IWA Benchmark Simulation Model No. 2 (BSM2). In a second series of simulations the parameters of the secondary settler model in the BSM2 are automatically changed on the basis of an on-line calculated risk of filamentous bulking, in order to mimic the effect of growth of filamentous bacteria in the plant. The results are presented using multivariate analysis. Including the effects of filamentous bulking in the simulation model gives a-more realistic-deterioration of the plant performance during periods when the conditions for development of filamentous bulking sludge are favourable: compared to the reference case where bulking effects are not considered. Thus, there is a decrease of the overall settling velocity, an accumulation of the total suspended solids (TSS) in the middle layers of the settler with a consequent reduction of their degree of compaction in the bottom. As a consequence there is a lower TSS concentration in both return and waste flow, less biomass in the bioreactors and a reduction of the TSS removal efficiency. The control alternatives using a TSS controller substantially increase the food to microorganisms (F/M) ratio in the bioreactor, thereby reducing both risk and effects of bulking sludge. The effects of ammonium (NH(4)(+)), nitrate (NO(3)(-)) and reject water control strategies are rather poor when it comes to handling solids separation problems.

Exploring Submerged Forward Osmosis for Water Recovery and Pre-Concentration of Wastewater Before Anaerobic Digestion: A Pilot Scale Study.

Applying forward osmosis directly on raw municipal wastewater is of high interest for the simultaneous production of a high quality permeate for water reuse and pre-concentrating wastewater for anaerobic digestion. This pilot scale study investigates, for the first time, the feasibility of concentrating real raw municipal wastewater using a submerged plate and frame forward osmosis module (0.34 m2) to reach 70% water recovery. Membrane performance, fouling behavior, and effective concentration of wastewater compounds were examined. Two different draw solutions (NaCl and MgCl2), operating either with constant draw concentration or in batch with draw dilution over time, were evaluated. Impact of gas sparging on fouling and external concentration polarization was also assessed. Water fluxes up to 15 L m-2 h-1 were obtained with clean water and 35 g NaCl/L as feed and draw solution, respectively. When using real wastewater, submerged forward osmosis proved to be resilient to clogging, demonstrating its suitability for application on municipal or other complex wastewater; operating with 11.7 g NaCl/L constant draw solution, water and reverse salt fluxes up to 5.1 ± 1.0 L m-2 h-1 and 4.8 ± 2.6 g m-2 h-1 were observed, respectively. Positively, total and soluble chemical oxygen demand concentration factors of 2.47 ± 0.15 and 1.86 ± 0.08, respectively, were achieved, making wastewater more suitable for anaerobic treatment.

Anaerobic membrane bioreactor for biogas production from concentrated sewage produced during sewer mining.

A laboratory scale anaerobic membrane bioreactor was operated for 11 months treating synthetic wastewater that mimicked the concentrate from a forward osmosis process treating municipal wastewater with 80% water recovery. The effect of temperature variation on reactor performance was assessed. The reactor operated during 4 months at 34 °C and then temperature was decreased to 23 °C, 17 °C and 15 °C mimicking the typical temperature seasonal variations of the sewage. Average COD removal efficiencies were 95, 87, 76 and 67% at 34, 23, 17 and 15 °C respectively, obtaining lower biogas production and lower COD removal at lower temperatures. Dissolved methane in the permeate averaged 8.2 mg CH4/L and did not significantly change with temperature. After 2 months operating at 15 °C, temperature was progressively increased, resulting in an immediate increase of methane production and COD removal efficiencies. Microbial analysis showed important changes in the archaeal community when temperature was changed from 34 to 23 °C.

Comparative assessment of endocrine disrupting compounds removal in heterotrophic and enriched nitrifying biomass.

Despite the number of studies that have investigated the fate of endocrine disrupting compounds (EDCs), to date results are still contradictory and more research is required to evaluate the contribution of the microbial communities present in different engineered treatment systems. Thus, autotrophic and heterotrophic types of biomass were here compared in terms of efficiency in the removal of estrone (E1), 17ß-estradiol (E2), estriol (E3), 17α-ethynilestradiol (EE2) and bisphenol A (BPA). Experiments were performed with enriched nitrifying activated sludge (NAS) and enriched ammonia oxidizing bacteria (AOB) sludge cultivated at lab-scale, as well as with conventional activated sludge (CAS) from a full-scale wastewater treatment plant. Both enriched NAS and AOB demonstrated a negligible degrading capacity. In both cases, the studied EDCs exhibited low removals (<14%) and showed no correlation with the increasing nitrification rates contradicting some of the hypothesis present in literature. Contrariwise, the biodegradation capabilities of the heterotrophic fraction of CAS were highlighted. E2 and E3 were removed by up to 100% and 78%, respectively. E1 was found to be the main transformation product of E2 (almost quantitative oxidation) and it was also highly eliminated. Finally, EE2 and BPA were more persistent biologically with removals ranging from 10% to 39%. For these two compounds similar removals were obtained during experiments with heat-inactivated biomass suggesting that sorption could be a relevant route of elimination.

Multi-criteria evaluation of wastewater treatment plant control strategies under uncertainty.

The evaluation of activated sludge control strategies in wastewater treatment plants (WWTP) via mathematical modelling is a complex activity because several objectives; e.g. economic, environmental, technical and legal; must be taken into account at the same time, i.e. the evaluation of the alternatives is a multi-criteria problem. Activated sludge models are not well characterized and some of the parameters can present uncertainty, e.g. the influent fractions arriving to the facility and the effect of either temperature or toxic compounds on the kinetic parameters, having a strong influence in the model predictions used during the evaluation of the alternatives and affecting the resulting rank of preferences. Using a simplified version of the IWA Benchmark Simulation Model No. 2 as a case study, this article shows the variations in the decision making when the uncertainty in activated sludge model (ASM) parameters is either included or not during the evaluation of WWTP control strategies. This paper comprises two main sections. Firstly, there is the evaluation of six WWTP control strategies using multi-criteria decision analysis setting the ASM parameters at their default value. In the following section, the uncertainty is introduced, i.e. input uncertainty, which is characterized by probability distribution functions based on the available process knowledge. Next, Monte Carlo simulations are run to propagate input through the model and affect the different outcomes. Thus (i) the variation in the overall degree of satisfaction of the control objectives for the generated WWTP control strategies is quantified, (ii) the contributions of environmental, legal, technical and economic objectives to the existing variance are identified and finally (iii) the influence of the relative importance of the control objectives during the selection of alternatives is analyzed. The results show that the control strategies with an external carbon source reduce the output uncertainty in the criteria used to quantify the degree of satisfaction of environmental, technical and legal objectives, but increasing the economical costs and their variability as a trade-off. Also, it is shown how a preliminary selected alternative with cascade ammonium controller becomes less desirable when input uncertainty is included, having simpler alternatives more chance of success.

Submerged Osmotic Processes: Design and Operation to Mitigate Mass Transfer Limitations.

Submerged forward osmosis (FO) is of high interest for bioreactors, such as osmotic membrane bioreactor, microalgae photobioreactor, food or bioproduct concentration where pumping through pressurized modules is a limitation due to viscosity or breakage of fragile components. However, so far, most FO efforts have been put towards cross flow configurations. This study provides, for the first time, insights on mass transfer limitations in the operation of submerged osmotic systems and offer recommendations for optimized design and operation. It is demonstrated that operation of the submerged plate and frame FO module requires draw circulation in the vacuum mode (vacuum assisted osmosis) that is in favor of the permeation flux. However, high pressure drops and dead zones occurring in classical U-shape FO draw channel strongly disadvantage this design; straight channel design proves to be more effective. External concentration polarization (ECP) is also a crucial element in the submerged FO process since mixing of the feed solution is not as optimized as in the cross flow module unless applying intense stirring. Among the mitigation techniques tested, air scouring proves to be more efficient than feed solution circulation. However, ECP mitigation methodology has to be adapted to application specificities with regards to combined/synergetic effects with fouling mitigation.

Advanced biological activated carbon filter for removing pharmaceutically active compounds from treated wastewater.

Through their release of effluents, conventional wastewater treatment plants (WWTPs) represent a major pollution point sources for pharmaceutically active compounds (PhACs) in water bodies. The combination of a biological activated carbon (BAC) filter coupled with an ultrafiltration (UF) unit was evaluated as an advanced treatment for PhACs removal at pilot scale. The BAC-UF pilot plant was monitored for one year. The biological activity of the biofilm that developed on the granular activated carbon (GAC) particles and the contribution of this biofilm to the overall removal of PhACs were evaluated. Two different phases were observed during the long-term monitoring of PhACs removal. During the first 9200 bed volumes (BV; i.e., before GAC saturation), 89, 78, 83 and 79% of beta-blockers, psychiatric drugs, antibiotics and a mix of other therapeutic groups were removed, respectively. The second phase was characterized by deterioration of the overall performances during the period between 9200 and 13,800 BV. To quantify the respective contribution of adsorption and biodegradation, a lab-scale setup was operated for four months and highlighted the essential role played by GAC in biofiltration units. Physical adsorption was indeed the main removal mechanism. Nevertheless, a significant contribution due to biological activity was detected for some PhACs. The biofilm contributed to the removal of 22, 25, 30, 32 and 35% of ciprofloxacin, bezafibrate, ofloxacin, azithromycin and sulfamethoxazole, respectively.