Identifying factors affecting irrigation metrics in the Haor basin using integrated Shannon's entropy, fuzzy logic and automatic linear model.

The sustainability of agricultural practices is seriously threatened by the quality of water used for irrigation. This paper aims to evaluate the suitability of irrigation water and identify the region suitable for agricultural use in the Haor basin of Bangladesh using conventional irrigation indices such as sodium adsorption ratio (SAR), percent sodium (Na%), magnesium hazard ratio (MHR), permeability index (PI), and Kelly's ratio (KR), as well as novel irrigation indices such as, Shannon's entropy index for irrigation water quality (EWQ) and fuzzy logic index for irrigation water quality (FIWQI). The main influences of groundwater and surface water parameters on irrigation indices were predicted using automatic linear modeling (ALM). Forty water samples were collected from shallow tube wells, rivers, canals, ponds, and drainage systems within agricultural land sampled and analyzed for cations and anions. SAR and KR show that 52.5% and 60% of the samples exceeded the allowable level, respectively, indicating that they were unsuitable for irrigation. According to EWQI, about 55% of the analyzed samples were of good quality, while 45% were of medium quality. ALM predicted that KR (0.98), Na% (0.87), and MHR (0.14) were the main significant factors affecting SAR and KR. ALM shows that elevated sodium, magnesium, and calcium are the most important factors affecting irrigation water suitability. The EWQI and FIWQI integrated models showed that water from nearly 30% of the sampling sites would need treatment before use. A new suitability map created by overlaying all parameters showed that surface water and some groundwater in the western and southwestern portions are suitable for agriculture. The north-central part is unsuitable for irrigation due to excessive sodium and magnesium levels. This paper will highlight the irrigation pattern for regional water resource use, identify new suitable regions, and improve sustainable agricultural practices in the Haor basin.

Human health exposure and risks of arsenic from contaminated soils and brinjal fruits collected from different producers and retailers levels.

A quantitative assessment was attempted to determine concentrations of total arsenic (As) in farmer's field soils and fruits of brinjal collected from two famous brinjals producing Upazila's, namely Melandaha and Islampur of Jamalpur district, Bangladesh. The study also evaluated cancer and non-cancer health risks for both males and females caused by dermal exposure of soils and dietary intake of brinjal grown in farmers' fields and sold at different markets of four country districts. The study findings revealed that 75% of soil sampling locations had enrichment factor (EFc) values > 1.5, indicating the anthropogenic sources of As, and 50% of the sites possessed EFc values within the range of 2.0-5.0 indicated moderate enrichment of As. The mean concentrations of As in brinjal grown in farmers' fields and retailers of different markets of four districts were 0.18 and 0.39 µg g-1, respectively. The soils of the study area exhibited negligible risk in terms of the calculated hazard quotient, hazard index and incremental lifetiame cancer risk (ILCR) values for As due to dermal and ingestion exposures. In contrast, the same values for As due to the dietary intake of brinjal were thousands of times greater than the threshold level in 40% of farmers' field and all retailers' levels samples. Compared to the producer/farmers' field samples, the calculated average non-carcinogenic and carcinogenic health risks were more than twice in samples collected from different retailers. The present study suggests further pinpoint investigation of potential entry routes of As in the supply chain through future traceability studies.

Comparative catalytic degradation of a metabolite 3,5-dichloroaniline derived from dicarboximide fungicide by laccase and MnO2 mediators.

A ternary catalysis system was investigated to evaluate the comparative degradation of toxic fungicide metabolite 3,5-dichloroaniline (3,5-DCA) by laccase and MnO2 with mediators. In this study, copper based fungal enzyme laccase (Trametes versicolor origin) and metal catalyst MnO2 with various combinations of phenolic mediators (catechol, syringaldehyde, syringic acid, caffeic acid and gallic acid) were monitored to optimize and screen the better one for 3,5-DCA degradation assay. Catechol showed better potentiality in reduction of 3,5-DCA among the studied mediators. Catechol (2mM) showed the highest reduction rate (99-100%) followed by syringaldehyde (40.51%) with 2U/mL of laccase at 25 °C within 24 h reaction time. Similarly, complete degradation of 3,5-DCA was obtained by catechol (2mM) with 2 mg/mL of MnO2 in MnO2-mediator assay. The notable finding of current study indicated the triggering of catechol for better 3,5-DCA degradation at higher pH condition but inertness in laccase-mediator assay due to laccase destabilization. The reaction pathways of optimized mediator-based catalysis for laccase and MnO2 were proposed. Finally, the optimized laccase-catechol based degradation was considered as a pioneer green catalysis approach to reduce the toxic metabolite 3,5-DCA concentrations in aqueous medium as compared to MnO2-catechol catalysis.

Residue Monitoring and Risk Assessment of Cyazofamid and Its Metabolite in Korean Cabbage Under Greenhouse Conditions.

The residual characteristics and risk assessment with respect to cyazofamid and its metabolite 4-chloro-5-p-tolylimidazole-2-carbonitrile were monitored in case of Korean cabbage at different preharvest intervals during a greenhouse trial. The 0.02 kg a.i/ha of cyazofamid was sprayed twice on seven-day intervals (i.e., on day 0, 7, 14, and 21 before harvest). The liquid chromatography-tandem mass spectrometry analysis was used to monitor the residual amount of fungicide. The matrix-matched calibration curves with respect to the cyazofamid in Korean cabbage exhibited good linearity (R2 ≥ 0.999) and acceptable recoveries of 84.1%-114.9%. The biological half-life of cyazofamid in Korean cabbage was 3.18 days. During the treatment, the preharvest residue of cyazofamid in Korean cabbage 14 days before harvest (0.80 mg/kg) was lower than that specified by the MFDS-MRL (Ministry of Food and Drug Safety-Maximum Residue Limit, 2.0 mg/kg) and should be recommended as the safe preharvest-interval application limit. The hazard quotient showed low toxicity (70.58%) during the risk assessment study of cyazofamid.

A critical review of sustainable pesticide remediation in contaminated sites: Research challenges and mechanistic insights.

Incidental pesticide application on farmlands can result in contamination of off-target biota, soil, groundwater, and surrounding ecosystems. To manage these pesticide contaminations sustainably, it is important to utilize advanced approaches to pesticide decontamination. This review assesses various innovative strategies applied for remediating pesticide-contaminated sites, including physical, chemical, biological, and nanoremediation. Integrated remediation approaches appear to be more effective than singular technologies. Bioremediation and chemical remediation are considered suitable and sustainable strategies for decontaminating contaminated soils. Furthermore, this study highlights key mechanisms underlying advanced pesticide remediation that have not been systematically studied. The transformation of applied pesticides into metabolites through various biotic and chemical triggering factors is well documented. Ex-situ and in-situ technologies are the two main categories employed for pesticide remediation. However, when selecting a remediation technique, it is important to consider factors such as application sites, cost-effectiveness, and specific purpose. In this review, the sustainability of existing pesticide remediation strategies is thoroughly analyzed as a pioneering effort. Additionally, the study summarizes research uncertainties and technical challenges associated with different remediation approaches. Lastly, specific recommendations and policy advocacy are suggested to enhance contemporary remediation approaches for cleaning up pesticide-contaminated sites.

Enhancing rice growth and yield with weed endophytic bacteria Alcaligenes faecalis and Metabacillus indicus under reduced chemical fertilization.

Endophytic bacteria, recognized as eco-friendly biofertilizers, have demonstrated the potential to enhance crop growth and yield. While the plant growth-promoting effects of endophytic bacteria have been extensively studied, the impact of weed endophytes remains less explored. In this study, we aimed to isolate endophytic bacteria from native weeds and assess their plant growth-promoting abilities in rice under varying chemical fertilization. The evaluation encompassed measurements of mineral phosphate and potash solubilization, as well as indole-3-acetic acid (IAA) production activity by the selected isolates. Two promising strains, tentatively identified as Alcaligenes faecalis (BTCP01) from Eleusine indica (Goose grass) and Metabacillus indicus (BTDR03) from Cynodon dactylon (Bermuda grass) based on 16S rRNA gene phylogeny, exhibited noteworthy phosphate and potassium solubilization activity, respectively. BTCP01 demonstrated superior phosphate solubilizing activity, while BTDR03 exhibited the highest potassium (K) solubilizing activity. Both isolates synthesized IAA in the presence of L-tryptophan, with the detection of nifH and ipdC genes in their genomes. Application of isolates BTCP01 and BTDR03 through root dipping and spraying at the flowering stage significantly enhanced the agronomic performance of rice variety CV. BRRI dhan29. Notably, combining both strains with 50% of recommended N, P, and K fertilizer doses led to a substantial increase in rice grain yields compared to control plants receiving 100% of recommended doses. Taken together, our results indicate that weed endophytic bacterial strains BTCP01 and BTDR03 hold promise as biofertilizers, potentially reducing the dependency on chemical fertilizers by up to 50%, thereby fostering sustainable rice production.

A pilot lab trial for enhanced oxidative transformation of procymidone fungicide and its aniline metabolite using heterogeneous MnO2 catalysts.

In this study, the feasibility of two heterogeneous catalysis (non-Fenton heterogeneous catalysis and catalytic ozonation) was evaluated for the oxidative transformation of the fungicide procymidone and its major metabolite (3,5-dichloroaniline; 3,5-DCA) under a pilot lab experiment. Among the studied treatments, only H2O2 or O3 significantly oxidized procymidone and 3,5-DCA. However, heterogeneous catalysis used with various types of MnO2 catalysts was found to be an effective rapid strategy for transformation of procymidone and its aniline metabolite. Among the studied catalysts, δ-MnO2 performed well in the enhanced oxidative transformation of procymidone and 3,5-DCA in MnO2-mediator system assay. The optimal reaction parameters, such as reaction pH, and initial catalyst concentration were comparatively evaluated. However, heterogeneous catalysis and catalytic ozonation were revealed as the rapid strategy for oxidative transformation of investigated procymidone and 3,5-DCA as compared to single oxidation by peroxide/ozone. Finally, as a novel insight of this investigation, a postulated reaction mechanism underlying the accelerated transformation of aniline metabolites via heterogeneous catalysis was explored. The findings of this study will open new avenues for evaluating heterogeneous catalysis during oxidative transformation of non-phenolic pollutants in both lab trial and field applications. This study can be expanded for use in actual field settings, using environmental samples from contaminated areas exposed to non-phenolic pesticides and their metabolites.

Environmental fate and metabolic transformation of two non-ionic pesticides in soil: Effect of biochar, moisture, and soil sterilization.

Soil moisture, organic matter, and soil microbes are the key considering factors that control the persistence, degradation, and transformation of applied pesticides under varied soil conditions. In this study, underlying influence of these factors was assessed through the fates and metabolic transformation of two non-ionic pesticides (e.g., Phorate and Terbufos) in soils. Concisely, two distinct experiments including a customized batch equilibrium (sorption study), and a lab incubation trial (degradation study) were performed, following the OECD guidelines. As per study findings, biochar (BC) amendment was found to be the most influential factors during sorption study, particularly, 1% BC amendment contributed to achieve the best results. In addition, the non-linearity of sorption isotherm (1/n < 1.0) was revealed through Freundlich isotherm, indicating the strong adsorption of studied pesticides onto the soils. On the other hand, during degradation study, soil moisture initiates the enhanced degradation of parent pesticides and subsequent metabolism. In the presence of 40% water holding capacity (WHC), 1% BC amendment enhances the metabolic transformation, while H2O2 treatment could hinder the process. Additionally, the half-life degradation (t1/2) of phorate and terbufos was controlled by biochar amendment, moisture, and soil sterilization, respectively. Finally, BC can accelerate the metabolic transformation, whereas, phorate underwent a metabolic change into sulfoxide and sulfone while terbufos turned into solely sulfoxide. This pioneering study gathered crucial data for understanding the persistence and metabolic transition of non-ionic pesticides in soils and their patterns of degradation.

Uptake and translocation of fungicide picarbutrazox in greenhouse cabbage: the significance of translocation factors and home processing.

This study evaluated the uptake and translocation of the fungicide picarbutrazox (PBZ) and its isomer in greenhouse cabbage. Two distinct treatments, including foliar spray and soil application of PBZ, were used in this study. In the foliar application, the fungicide was sprayed thrice at intervals of 7 days from 30, 21, and 14 days before harvest following the OECD guidelines of fungicides in crops, whereas in soil treatment, PBZ was applied for one time at concentrations of 2 and 10 mg/kg, and cabbage was cultivated for 68 days. Additionally, the role of root and translocation factors during residual fungicide distribution was demonstrated. The quality control of the analytical study exhibited excellent linearity (R2 ≥ 0.99), the limit of quantification (LOQ 0.005 mg/kg), accuracy (recovery within the range of 70-120%), and precision (relative coefficient within 0.3-13.8%) for studied PBZ and its metabolites. In the foliar application, initially higher amount of residual PBZ was evident in the outermost leaf of the cabbage, whereas in soil treatment, the highest residual PBZ was observed in the soil and roots. Therefore, the application method of picarbutrazox is a critical factor for defining the initial entry route of pesticides and the subsequent translocations through the investigated crops.

Biological and green remediation of heavy metal contaminated water and soils: A state-of-the-art review.

Contamination of the natural ecosystem by heavy metals, organic pollutants, and hazardous waste severely impacts on health and survival of humans, animals, plants, and microorganisms. Diverse chemical and physical treatments are employed in many countries, however, the acceptance of these treatments are usually poor because of taking longer time, high cost, and ineffectiveness in contaminated areas with a very high level of metal contents. Bioremediation is an eco-friendly and efficient method of reclaiming contaminated soils and waters with heavy metals through biological mechanisms using potential microorganisms and plant species. Considering the high efficacy, low cost, and abundant availability of biological materials, particularly bacteria, algae, yeasts, and fungi, either in natural or genetically engineered (GE) form, bioremediation is receiving high attention for heavy metal removal. This report comprehensively reviews and critically discusses the biological and green remediation tactics, contemporary technological advances, and their principal applications either in-situ or ex-situ for the remediation of heavy metal contamination in soil and water. A modified PRISMA review protocol is adapted to critically assess the existing research gaps in heavy metals remediation using green and biological drivers. This study pioneers a schematic illustration of the underlying mechanisms of heavy metal bioremediation. Precisely, it pinpoints the research bottleneck during its real-world application as a low-cost and sustainable technology.

Microplastic as an invisible threat to the coral reefs: Sources, toxicity mechanisms, policy intervention, and the way forward.

Microplastic (MP) pollution waste is a global macro problem, and research on MP contamination has been done in marine, freshwater, and terrestrial ecosystems. Preventing MP pollution from hurting them is essential to maintaining coral reefs' ecological and economic benefits. However, the public and scientific communities must pay more attention to MP research on the coral reef regions' distribution, effects, mechanisms, and policy evaluations. Therefore, this review summarizes the global MP distribution and source within the coral reefs. Current knowledge extends the impacts of MP on coral reefs, existing policy, and further recommendations to mitigate MPs contamination on corals are critically analyzed. Furthermore, mechanisms of MP on coral and human health are also highlighted to pinpoint research gaps and potential future studies. Given the escalating plastic usage and the prevalence of coral bleaching globally, there is a pressing need to prioritize research efforts on marine MPs that concentrate on critical coral reef areas. Such investigations should encompass an extensive and crucial understanding of the distribution, destiny, and effects of the MPs on human and coral health and the potential hazards of those MPs from an ecological viewpoint.

A critical review of sustainable application of biochar for green remediation: Research uncertainty and future directions.

Biochar, a carbon-rich material produced from the pyrolysis of organic biomass, has gained significant attention as a potential solution for sustainable green remediation practices. Several studies analyze biomass-derived biochar techniques and environmental applications, but comprehensive assessments of biochar limitations, uncertainty, and future research directions still need to be improved. This critical review aims to present a comprehensive analysis of biochar's efficacy in environmental applications, including soil, water, and air, by sequentially addressing its preparation, application, and associated challenges. The review begins by delving into the diverse methods of biochar production, highlighting their influence on physical and chemical properties. This review explores the diverse applications of biochar in remediating contaminated soil, water, and air while emphasizing its sustainability and eco-friendly characteristics. The focus is on incorporating biochar as a remediation technique for pollutant removal, sequestration, and soil improvement. The review highlights the promising results obtained from laboratory-scale experiments, field trials, and case studies, showcasing the effectiveness of biochar in mitigating contaminants and restoring ecosystems. The environmental benefits and challenges of biochar production, characterization, and application techniques are critically discussed. The potential synergistic effects of combining biochar with other remediation methods are also explored to enhance its efficacy. A rigorous analysis of the benefits and drawbacks of biochar for diverse environmental applications in terms of technical, environmental, economic, and social issues is required to support the commercialization of biochar for large-scale uses. Finally, future research directions and recommendations are presented to facilitate the development and implementation of biochar-based, sustainable green remediation strategies.

A critical review and prospect of NO2 and SO2 pollution over Asia: Hotspots, trends, and sources.

Nitrogen dioxide (NO2) and sulfur dioxide (SO2) are two major atmospheric pollutants that significantly threaten human health, the environment, and ecosystems worldwide. Despite this, only some studies have investigated the spatiotemporal hotspots of NO2 and SO2, their trends, production, and sources in Asia. Our study presents a literature review covering the production, trends, and sources of NO2 and SO2 across Asian countries (e.g., Bangladesh, China, India, Iran, Japan, Pakistan, Malaysia, Kuwait, and Nepal). Based on the findings of the review, NO2 and SO2 pollution are increasing due to industrial activity, fossil fuel burning, biomass burning, heavy traffic movement, electricity generation, and power plants. There is significant concern about health risks associated with NO2 and SO2 emissions in Bangladesh, China, India, Malaysia, and Iran, as they pay less attention to managing and controlling pollution. Even though the lack of quality datasets and adequate research in most Asian countries further complicates the management and control of NO2 and SO2 pollution. This study has NO2 and SO2 pollution scenarios, including hotspots, trends, sources, and their influences on Asian countries. This study highlights the existing research gaps and recommends new research on identifying integrated sources, their variations, spatiotemporal trends, emission characteristics, and pollution level. Finally, the present study suggests a framework for controlling and monitoring these two pollutants' emissions.

A pilot study for enhanced transformation of a metabolite 3,5-dichloroaniline derived from dicarboximide fungicides through immobilized laccase mediator system.

This pilot investigation aimed to evaluate the removal efficiency and the underlying biocatalytic pathways of immobilized fungal laccase during the oxidative biotransformation of a non-phenolic metabolite, 3,5-dichloroaniline (3,5-DCA) derived from dicarboximide fungicides. The maximum loading of laccase on the microporous support surfaces could reach 36.4 mg/g. The immobilized laccase on the microporous support surfaces exhibited excellent thermal stability, pH adaptability, storage stability, and reusability compared to free laccase. The ILMS assay indicated that the immobilized laccase efficiently removed studied 3,5-DCA (99-100%) in the aqueous medium, within 72 h in the presence of catechol. In this study, we identified three coupling reaction products during the removal of 3,5-DCA through an ILMS assay. Based on the identified coupling reaction products, we proposed the reaction pathway for the biotransformation of 3,5-DCA by immobilized laccase, which was shown to be potentially useful in the sustainable environmental remediation of aniline metabolite (i.e., 3,5-DCA) derived from dicarboximide fungicides.

Integrated biorefinery approach to valorize citrus waste: A sustainable solution for resource recovery and environmental management.

Citrus fruits are extensively cultivated, consumed and major processed horticulture crops around the globe. High processing and consumption generate huge quantities of solid organic wastes. Citrus waste represents approximately 40-50% of total fruit weight, which consists of rag (membranes and cores), pulp, seeds, and peel (albedo and flavedo), which are a potential source of value-added products including essential oils, carotenoids, pectin, dietary fibers, and polyphenols biofuel, etc. However, waste produced is discarded as waste in the environment, which causes a serious threat due to the presence of bioactive compounds. Recent research strategies on the integrated biorefinery approach explore various ways to utilize the waste obtained from the citrus wastes for their subsequent recovery of value-added products. Moreover, the citrus waste can be turned into various bio-products, viz., enzymes, biofuels, and biopolymers using the integrated biorefinery approach, which can optimize the development of green waste for sustainability and economic benefits. Given the sustainable solution for resource recovery and environmental management, the article reviews the latest advances in the novel valorization approach and valuation of the existing state-of-the-art green technologies for citrus waste utilization to bring a sustainable solution for increasing demand for food, fuel, and energy security. To achieve the zero-waste approach and industrial viability, more efforts should be given to scale-up green recovery techniques along with diverse product profiling.

Optimization of a Multi-Residue Analytical Method during Determination of Pesticides in Meat Products by GC-MS/MS.

In this study, a multi-residue analysis was developed for 32 compounds, including pesticides and metabolites, in five meat products using gas chromatography-tandem mass spectrometry (GC-MS/MS). The validation of the developed analytical method was also evaluated in accordance with Codex Alimentarius guidelines. Aminopropyl (NH2), C18, and florisil solid phase extraction (SPE) cartridges were used to evaluate and optimize the cleanup procedure of the tested samples prior to GC-MS/MS analysis. Based on the analytical performance, the C18 SPE cartridge was deemed to be the most suitable among the examined SPE cartridges. The optimized method demonstrated that 29 out of 32 tested compounds acquired good linearity (R2 ≥ 0.99), and 25 tested compounds displayed the method limit of quantification (MLOQ) ≤ 0.01 mg/kg. Out of the 32 tested compounds, only 21 compounds met the acceptable analytical criteria for the lard and tallow samples, compared to 27 compounds in the beef, pork, and chicken samples that falls within the acceptable standards for recovery (70-120%) and analytical precision (relative standard deviation RSD ≤ 20%). The average matrix effect was widely varied (20.1-64.8%) in the studied meat samples that were affected by either ion enhancement or suppression. In particular, in the lard sample, 13 compounds showed poor recovery and analytical precision due to ion suppression. Thus, the matrix effect (ME) was considered a critical factor during multi-residue pesticide analysis in different meat products. In conclusion, this developed analytical method can be used as a routine monitoring system for residual pesticide analysis in livestock products with acceptable analytical standards. Further meticulous analytical studies should be optimized and validated for multi-residue pesticide analysis in diversified meat products.

Heavy metals contamination and associated health risks in food webs-a review focuses on food safety and environmental sustainability in Bangladesh.

Heavy metals occur naturally in very small amounts in living organisms, but exposure to their higher concentrations is hazardous. Heavy metals at hazardous levels are commonly found in foodstuffs of Bangladesh, mainly due to the lack of safety guidelines and poor management of industrial effluents. Several lines of evidence suggest that the level of heavy metals in foodstuffs of Bangladesh is higher than the acceptable limits set by World Health Organization/Food and Agriculture Organization. Literature survey revealed that the sources and transport pathways of heavy metals in the ecosystem and the abundance of heavy metals in the food products of Bangladesh are potential threats to food safety. However, an extensive assessment of the toxicity of heavy metals in food webs is lacking. Although widespread heavy metal contamination in various foodstuffs and environmental matrices have been summarized in some reports, a critical evaluation regarding multi-trophic transfer and the health risk of heavy metal exposure through food chain toxicity in Bangladesh has not been performed. This systematic review critically discussed heavy metal contamination, exposure toxicity, research gaps, existing legislation, and sustainable remediation strategies to enhance Bangladesh's food safety. In particular, this study for the first time explored the potential multi-trophic transfer of heavy metals via food webs in Bangladesh. Furthermore, we recommended a conceptual policy framework to combat heavy metal contaminations in Bangladesh.

Marine Natural Product Antimycin A Suppresses Wheat Blast Disease Caused by Magnaporthe oryzae Triticum.

The application of chemical pesticides to protect agricultural crops from pests and diseases is discouraged due to their harmful effects on humans and the environment. Therefore, alternative approaches for crop protection through microbial or microbe-originated pesticides have been gaining momentum. Wheat blast is a destructive fungal disease caused by the Magnaporthe oryzae Triticum (MoT) pathotype, which poses a serious threat to global food security. Screening of secondary metabolites against MoT revealed that antimycin A isolated from a marine Streptomyces sp. had a significant inhibitory effect on mycelial growth in vitro. This study aimed to investigate the inhibitory effects of antimycin A on some critical life stages of MoT and evaluate the efficacy of wheat blast disease control using this natural product. A bioassay indicated that antimycin A suppressed mycelial growth (62.90%), conidiogenesis (100%), germination of conidia (42%), and the formation of appressoria in the germinated conidia (100%) of MoT at a 10 µg/mL concentration. Antimycin A suppressed MoT in a dose-dependent manner with a minimum inhibitory concentration of 0.005 µg/disk. If germinated, antimycin A induced abnormal germ tubes (4.8%) and suppressed the formation of appressoria. Interestingly, the application of antimycin A significantly suppressed wheat blast disease in both the seedling (100%) and heading stages (76.33%) of wheat at a 10 µg/mL concentration, supporting the results from in vitro study. This is the first report on the inhibition of mycelial growth, conidiogenesis, conidia germination, and detrimental morphological alterations in germinated conidia, and the suppression of wheat blast disease caused by a Triticum pathotype of M. Oryzae by antimycin A. Further study is required to unravel the precise mode of action of this promising natural compound for considering it as a biopesticide to combat wheat blast.

Dissipation characteristics of spirotetramat and its metabolites in two phenotypically different Korean vegetables under greenhouse conditions.

This study involved analysis and method validation of spirotetramat applied to two phenotypically different Korean vegetables (e.g. Korean cabbage and shallots) to determine the safe pre-harvest residue limit (PHRL) and comparative dissipation patterns. Two steps of the investigation involved greenhouse monitoring during crop cultivation followed by LC-MS/MS analysis. Commercial spirotetramat was sprayed twice with seven-day intervals according to the spray schedule (0, 3, 7, 10, 14, and 21 days before harvest) at the dose recommended by the Ministry of Food and Drug Safety (MFDS), Korea. During the validation of the analytical method, good linearity, specificity, and acceptable recoveries (82%-114% for Korean cabbage and 82%-111% for shallot) were established for spirotetramat and its four metabolites. The calculated biological half-life derived from the first-order reaction (t1/2) of spirotetramat was 4.8 days for Korean cabbage and 4.0 days for shallot, respectively. The safe PHRL for Korean cabbage was suggested at 7 days, due to permissible spirotetramat concentration in terms of an acceptable MRL. The findings of the study will be used as the analytical reference point for developing spirotetramat safety guidelines for use in the vegetables investigated.

A comprehensive review of heavy metal pollution in the coastal areas of Bangladesh: abundance, bioaccumulation, health implications, and challenges.

The coastal zone of Bangladesh, with a population density of 1278 people per square kilometer, is under serious threat due to heavy metal pollution. To date, many studies have been conducted on the heavy metal contamination in soils, water, aquatic animals, and plants in the coastal zone of Bangladesh; however, the available information is dispersed. In this study, previous findings on the contamination levels, distributions, risks, and sources of heavy metals in sediments and organisms were summarized for the first time to present the overall status of heavy metal pollution along coastal regions. Earlier research found that the concentrations of various heavy metals (HMs), particularly Co, Cd, Pb, Cu, Cr, Mn, Fe, and Ni in water, sediment, and fish in most coastal locations, were above their permissible limits. High concentrations of HMs were observed in sediments and water, like Cr of 55 mg/kg and 86.93 mg/l in the ship-breaking areas and Karnaphuli River, respectively, in coastal regions of Bangladesh. Heavy metals severely contaminated the Karnaphuli River estuary and ship-breaking area on the Sitakundu coast, where sediments were the ultimate sink of high concentrations of metals. Sedentary or bottom-dwelling organisms like gastropods and shrimp had higher levels of heavy metals than other organisms. As a result, the modified PRISMA review method was used to look at the critical research gap about heavy metal pollution in Bangladesh's coastal areas by analyzing the current research trends and bottlenecks.