Deciphering Sodium-Ion Storage: 2D-Sulfide versus Oxide Through Experimental and Computational Analyses.

Transition metal derivatives exhibit high theoretical capacity, making them promising anode materials for sodium-ion batteries. Sulfides, known for their superior electrical conductivity compared to oxides, enhance charge transfer, leading to improved electrochemical performance. Here, a hierarchical WS2 micro-flower is synthesized by thermal sulfurization of WO3. Comprising interconnected thin nanosheets, this structure offers increased surface area, facilitating extensive internal surfaces for electrochemical redox reactions. The WS2 micro-flower demonstrates a specific capacity of ≈334 mAh g-1 at 15 mA g-1, nearly three times higher than its oxide counterpart. Further, it shows very stable performance as a high-temperature (65 °C) anode with ≈180 mAh g-1 reversible capacity at 100 mA g-1 current rate. Post-cycling analysis confirms unchanged morphology, highlighting the structural stability and robustness of WS2. DFT calculations show that the electronic bandgap in both WS2 and WO3 increases when going from the bulk to monolayers. Na adsorption calculations show that Na atoms bind strongly in WO3 with a higher energy diffusion barrier when compared to WS2, corroborating the experimental findings. This study presents a significant insight into electrode material selection for sodium-ion storage applications.

Experimental and theoretical insights into the supercapacitive performance of interconnected WS2 nanosheets.

Transition metal dichalcogenides (TMDs) are fascinating and prodigious considerations in the electrochemical energy storage sector because of their two dimensional chemistry as well as heterogeneous characteristics. Herein, we synthesized interconnected WS2 nanosheets by a hydrothermal method followed by sulphuration at 850 °C in an argon atmosphere. The ultrathin WS2 nanosheet array is endowed with an excellent specific capacitance of 74 F g-1 at the current density of 3 A g-1 up 7000 cycles. Moreover, a symmetric supercapacitor was fabricated using WS2 nanosheets, which provided the admirable high specific capacity of 6.3 F g-1 at 0.05 A g-1 with the energy and power density of 5.6 × 102 mW h kg-1 and 3.6 × 10 5 mW kg-1, respectively. Density functional theory (DFT) simulations revealed the presence of populated energy states near the Fermi level resulting in a high quantum capacitance value, which supports the experimentally achieved high capacitance value. The attained results recommend interconnected WS2 nanosheets as a novel, robust, and low-cost electrode material for supercapacitor energy storage devices.

3D-engineered WO3 microspheres assembled by 2D nanosheets with superior sodium storage capacity.

Because of the inadequate sodium storage capacity of graphite, the exploration of high-performance SIB anodes is a crucial step forward. Herein, we report the hydrothermally synthesized self-assembled interconnected nanosheets of WO3 microspheres possessing admirable sodium storage in terms of cycling stability and acceptable rate capability. Benefitting from the interconnected nature of the nanosheets with a hollow interior, the WO3 microspheres exhibited a high sodiation capacity of 431 mA h g-1 at 100 mA g-1 and an excellent rate performance of 60 mA h g-1 at 500 mA g-1 with an impressive coulombic efficiency of around 99%. Importantly, even after continuous cycling with increasing current densities, a specific capacity as high as 220 mA h g-1 could be recovered at a current density of 50 mA g-1, suggesting excellent sodium storage reversibility.

Carbon spheres decorated-graphene oxide framework as an excellent active material for redox flow battery and supercapacitors.

Composite of dextrose-derived oxygen-rich carbon spheres and graphene oxide, synthesised using a cost-effective and easy hydrothermal process, was used as an active material in two of the trending and promising energy storage devices. The surface morphology and properties of the composite were studied using scanning electron microscope, X-ray diffractometer, energy dispersive X-ray analysis, elemental mapping and Raman spectra. To analyse the electrochemical behaviour of the material, several electrochemical techniques such as cyclic voltammetry (CV), chronopotentiometry, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarisation study were used. The reversibility of Fe2+/Fe3+ redox species and resistance offered by electrolyte towards the modified electrode were studied using CV, EIS and Tafel studies. Further evaluation of efficacy of the active material towards the iron redox flow battery (IRFB) of 132 cm2 area was analysed by performing charge discharge studies at varied current densities. Substantial increase in the electrochemical performance of the IRFB with a coulombic efficiency (CE) 93% along with the good life cycle stability up to 25 cycles was observed. The composite was also used as a superior electrode material for supercapacitor application resulting in significant enhancement in the electrochemical performance with specific capacitance of 610 F g-1 and CE of 83% with 93% retention up to 1600 cycles.