Enhanced Stability and Catalytic Activity of a Nanocatalyst with Reusable Ionic Liquid Hydrogels for the Reduction of Organic Pollutants.

Nitroaromatic compounds have a wide range of applications. However, they pose a significant threat to both the environment and human health. Ionic liquid hydrogels (ILs-gels) have emerged as a cost-effective and environmentally friendly option for various applications. However, conventional ILs-gels are known to possess mechanical flaws or defects. The procedure utilized a facile synthesis route that involved the polymerization of acrylamide (AM) and ionic liquids (ILs) to create a novel candidate for nanoparticle absorption. This study resolved this issue by creating toughened hydrophobic combined hydrogels synthesized through the addition of SiO2@poly(butyl acrylate) core-shell inorganic-organic hybrid latex particles (SiO2@PBA) to the AM-ILs mixture. The SiO2@PBA particles were chosen to provide the hydrogels with exceptional stretchability (up to 4050% strain) and high mechanical properties (tensile strength of 126 kPa) by acting as both a nanotoughener and a cross-linking point for hydrophobic linkage. Additionally, the P(AM/ILs)-SiO2@PBA hydrogel served as a template for the in situ and stable formation of palladium (Pd) nanoparticles. By incorporation of these Pd nanoparticles as catalysts into P(AM/ILs)-SiO2@PBA hydrogel carriers, the resulting P(AM/ILs)-SiO2@PBA/Pd hydrogels exhibited the ability to catalyze the degradation of p-nitrophenol. Remarkably, even after 15 applications, the efficiency of the degradation process remained consistently above 90%. Thus, the innovative SiO2@PBA toughened ILs-hydrogel design strategy can be utilized to develop robust and stretchable hydrogel materials for catalytic use in the sewage disposal industry.

Synergistic Interaction of Ionic Liquid Grafted Poly(vinylidene Fluoride) and Carbon Nanotubes to Construct Water Treatment Membranes with Multiple Separation Properties.

In this study, the dual strategy of 1-butyl-3-vinylimidazolium bromide ionic liquid (IL) grafting and carbon nanotubes (CNTs) nanocomposition was applied to modify poly(vinylidene fluoride) (PVDF)-based membranes. The highly hydrophilic/oleophobic and fouling-resistant PVDF-g-IL/CNTs membranes with excellent separation efficiency were obtained by the nonsolvent-induced phase separation method with ethanol-water mixed solution as the coagulation bath. The grafted IL not only generated hydrophilic groups on PVDF chains but also acted together with the CNTs to induce the formation of hydrophilic ß-crystalline phase of PVDF, which significantly improved the hydrophilicity and pore structure of the modified PVDF membranes. As a result, the pure water flux of the optimal membrane increased up to 294.2 L m-2 h-1, which was 5.2 times greater than that of the pure PVDF membrane. Simultaneously, the electrostatic interaction of the positive IL and the integration of CNTs enhanced adsorption sites of the membranes, producing exceptional retention and adsorption of dye wastewater and oil-water emulsion. This study presents a straightforward and efficient approach for fabricating PVDF separation membranes, which have potential applications in the purification of various polluted wastewater.

Efficient Meta-couplers Squeezing Propagating Light into On-Chip Subwavelength Devices in a Controllable Way.

On-chip photonic systems play crucial roles in nanoscience and nanoapplications, but coupling external light to these subwavelength devices is challenging due to a large mode mismatch. Here, we establish a new scheme for realizing highly miniaturized couplers for efficiently exciting on-chip photonic devices in a controllable way. Relying on both resonant and Pancharatnam-Berry mechanisms, our meta-device can couple circularly polarized light to a surface plasmon, which is then focused into a spot placed with a target on-chip device. We experimentally demonstrate two meta-couplers. The first can excite an on-chip waveguide (with a 0.1λ × 0.2λ cross section) with an absolute efficiency of 51%, while the second can achieve incident spin-selective excitation of a dual-waveguide system. Background-free excitation of a gap-plasmon nanocavity with the local field enhanced by >1000 times is numerically demonstrated. Such a scheme connects efficiently propagating light in free space and localized fields in on-chip devices, being highly favored in many integration-optics applications.

High-efficiency plasmonic vortex generation with near-infrared bifunctional metasurfaces.

Plasmonic vortices have shown a wide range of applications in on-chip photonics due to their fascinating properties of the orbital angular momenta (OAM) and phase singularity. However, conventional devices to generate them suffer from issues of low efficiencies and limited functionalities. Here, we establish a systematic scheme to construct high-efficiency bifunctional metasurfaces that can generate two plasmonic vortices exhibiting distinct topological charges, based on a series of reflective meta-atoms exhibiting tailored reflection-phases dictated by both resonant and geometric origins. As a benchmark test, we first construct a meta-coupler with meta-atoms exhibiting geometric phases only, and experimentally demonstrate that it can generate a pre-designed plasmonic vortex at the wavelength of 1064 nm with an efficiency of 27% (56% in simulation). Next, we design/fabricate two bifunctional metasurfaces with meta-atoms integrated with both resonant and geometric phases, and experimentally demonstrate that they can generate divergent (or focused) or convergent (or defocused) plasmonic vortices with district OAM as shined by circularly polarized light with opposite helicity at 1064 nm wavelength. Our work provides an efficient platform to generate plasmonic vortices as desired, which can find many applications in on-chip photonics.

Methyl Methacrylate-co-glycidyl Methacrylate-Based Dielectric Films with High Breakdown Strength and Discharge Energy Density Tailored by PVDF.

Linear dielectric polymers are potential candidates for electrostatic capacitors due to their high breakdown strength, high efficiency, and low dielectric loss. In this work, a novel poly (vinylidene fluoride) (PVDF) tailored linear PMMA-co-GMA (MG) copolymer-based all-organic dielectric film with high breakdown strength and discharge energy density was prepared by the solution blending method. Compared with the PMMA homopolymer, the MG copolymer behaved with a higher energy density (5.6 J/cm3) since the GMA component bestowed higher polarity and yielded deep traps for the copolymer. On the other hand, the introduction of PVDF into MG further improved the dielectric constant and overcame the brittleness of MG films. When the concentration of PVDF was 30 wt %, the MG/PVDF film exhibited a high discharged energy density of 10.8 J/cm3 at 600 MV/m with a 78.7% discharge efficiency, which was 2.5 times that of pure PVDF (4.3 J/cm3 at 320 MV/m) and 1.9 times that of pure MG (5.6 J/cm3 at 460 MV/m). The improvement in energy storage performance might be ascribed to the excellent thermodynamic miscibility and hydrogen bond interaction between the linear MG copolymer and the ferroelectric PVDF. This research provides a new and feasible strategy for designing all-organic dielectric films with high energy density for energy storage applications.

Self-Cleaning and Photodegradable PVDF-g-IL Dye Wastewater Separation Membranes Modified with Dopamine-Coated TiO2 Core-Shell Particles.

In the present work, self-cleaning membranes of ionic liquid-grafted poly(vinylidene fluoride) (PVDF) polydopamine-coated TiO2 were prepared through a nonsolvent-induced phase separation method. PDA facilitates the uniform dispersion of TiO2 nanoparticles in PVDF substrates; meanwhile, TiO2@PDA core-shell particles and the hydrophilic IL improve the hydrophilicity of PVDF membranes and contribute to the increased average pore size and porosity, significantly improving the pure water permeation flux and dye wastewater flux (the water flux increased to 385.9 Lm-2 h-1). In addition, the combined effect of the positively charged IL and the strongly viscous PDA shell layer enhanced the retention and adsorption of dyes so that the retention and adsorption rates of both anionic and cationic dyes were close to 100%. Notably, the hydrophilic PDA allowed more TiO2 to migrate to the membrane surface during the phase transition; on the other hand, dopamine could promote photodegradation. Therefore, the combined two factors for TiO2@PDA were beneficial to the ultraviolet-catalytic (UV-catalytic) degradation of dyes on the surface of the membrane, leading to >80% degradation rates of various dyes. Thus, the high-efficiency and easy-to-operate wastewater treatment technology provides attractive potential for dye removal and resolution of membrane contamination.

High Strength, Conductivity, and Bacteriostasis of the P(AM-co-AA)/Chitosan Quaternary Ammonium Salt Composite Hydrogel through Ionic Crosslinking and Hydrogen Bonding.

Traditional hydrogels with a single-crosslinked network structure suffer from poor stretchability, low sensitivity, and easy contamination, which seriously affect their practical application in the strain sensor field. To overcome these shortcomings, herein, a multiphysical crosslinking strategy (ionic crosslinking and hydrogen bonding) was designed to prepare a hydrogel strain sensor based on chitosan quaternary ammonium salt (HACC)-modified P(AM-co-AA) (acrylamide-co-acrylic acid copolymer) hydrogels. The ionic crosslinking for the double-network P(AM-co-AA)/HACC hydrogels was achieved by an immersion method with Fe3+ as crosslinking sites, which crosslinked with the amino group (-NH2) on HACC and the carboxyl group (-COOH) on P(AM-co-AA) and enabled the hydrogels to recover and reorganize rapidly, resulting in a hydrogel-based strain sensor with excellent tensile stress (3 MPa), elongation (1390%), elastic modulus (0.42 MPa), and toughness (25 MJ/m3). In addition, the prepared hydrogel exhibited high electrical conductivity (21.6 mS/cm) and sensitivity (GF = 5.02 at 0-20% strain, GF = 6.84 at 20-100% strain, and GF = 10.27 at 100-480% strain). Furthermore, the introduction of HACC endowed the hydrogel with excellent antibacterial properties (up to 99.5%) and excellent antibacterial activity against bacteria of three forms, bacilli, cocci, and spores. The flexible, conductive, and antibacterial hydrogel can be applied as a strain sensor for real-time detection of human motions such as joint movement, speech, and respiration, which exhibits a promising application prospect in wearable devices, soft robotic systems, and other fields.

Carbon Nanotubes and Silica@polyaniline Core-Shell Particles Synergistically Enhance the Toughness and Electrical Conductivity in Hydrophobic Associated Hydrogels.

Soft, conductive, and stretchable sensors are highly desirable in many applications, including artificial skin, biomonitoring patches, and so on. Recently, a combination of good electrical and mechanical properties was regarded as the most important evaluation criterion for judging whether hydrogel sensors are suitable for practical applications. Herein, we demonstrate a novel carboxylated carbon nanotube (MWCNT-COOH)-embedded P(AM/LMA)/SiO2@PANI hydrogel. The hydrogel benefits from a double-network structure (hydrogen bond cross-linking and hydrophobic connectivity network) due to the role of MWCNT-COOH and SiO2@PANI as cross-linkers, thus resulting in tough composite hydrogels. The obtained P(AM/LMA)/SiO2@PANI/MWCNT-COOH hydrogels exhibited high tensile strength (1939 kPa), super stretchability (3948.37%), and excellent strain sensitivity (gauge factor = 11.566 at 100-1100% strain). Obviously, MWCNT-COOH not only improved the electrical conductivity but also enhanced the mechanical properties of the hydrogel. Therefore, the integration of MWCNT-COOH and SiO2@PANI-based hydrogel strain sensors will display broad application in sophisticated intelligence, soft robotics, bionic prosthetics, personal health care, and other fields using inexpensive, green, and easily available biomass.

Crosslinking modification and hydrogen bonding synergy to achieve high breakdown strength and energy density of PMMA-co-GMA/PVDF dielectric composite films.

Polymer-based dielectric materials have been used in film capacitors due to their rapid charge-discharge rate, lightness, and low cost. Nevertheless, the energy storage properties of these dielectric films were limited by their weak polarization ability and low discharge energy density. Herein, the solution casting method was used to prepare all-organic crosslinked composite films using linear methyl methacrylate-co-glycidyl methacrylate (MG) as the matrix and ferroelectric poly(vinylidene fluoride) (PVDF) as the organic filler. The crosslinked MG networks can enhance the breakdown strength, restrain dielectric loss, and keep high discharge efficiency. What's more, the presence of PVDF can compensate for the low electrical displacement, improve the permittivity, and overcome the brittleness of the crosslinked films. The optimal all-organic crosslinked dielectric film exhibited an ultrahigh breakdown strength of 800 MV m-1 and a high efficiency of 77.4%. The maximum energy density of the composite film reached up to 12.1 J cm-3, which was nearly 120% higher than the energy density of 5.6 J cm-3 of the pure MG film. The enhancement in energy storage properties is ascribed to the synergistic effects of chemical crosslinking and hydrogen bonding. This study offers a feasible method for all-organic polymer films to fabricate energy storage equipment.

All-organic PVDF-based composite films with high energy density and efficiency synergistically tailored by MMA-co-GMA copolymer and cyanoethylated cellulose.

All-organic polymer dielectric films have been widely used for different electrical devices in recent years. However, their development is impeded by low Ue and large device volume. In the present paper, polyvinylidene fluoride (PVDF) composite dielectric materials, with high energy density (Ue) and energy efficiency (η), were prepared through the synergistic effect of a new MMA-co-GMA (MG) copolymer and cyanoethylated cellulose. MG was miscible with PVDF, which reduced the dielectric loss (tan δ) and improved the η of PVDF due to the linear structure and the hydrogen bonding interaction with the epoxy groups for MG. To further enhance the Ue of the dielectric films, cyanoethylated cellulose (CR-C) was added as a third component into the PVDF composite matrix to improve the Ue. The deep trap effect of hydrogen bonds between PVDF/MG and CR-C improved the electric breakdown strength (Eb) of the three-phase composite films from 440 MV m-1 to 640 MV m-1. Moreover, the high polarization of cyanoethylated cellulose can significantly improve the Ue (24.43 J cm-3) of the three-phase composite dielectric film, and the efficiency can be maintained above 75% at 640 MV m-1. This research provides a new idea for the manufacturing of homogeneous and stable all-organic PVDF dielectric composite films based on the hydrogen bonding construction strategy.

All-dielectric orthogonal doublet cylindrical metalens in long-wave infrared regions.

Metalens have been recently introduced to overcome shortcomings of traditional lenses and optical systems, such as large volume and complicated assembly. As a proof-of-principle demonstration, we design an all-dielectric converging cylindrical metalens (CML) for working in long-wave infrared regions around 9 µm, which is made up of silicon-pillar on MgF2 dielectric layer. We further demonstrate the focusing effect of an orthogonal doublet cylindrical metalens (ODCM). Two CMLs are combined orthogonally and a circular focusing spot was demonstrated. This proves that within a certain size range, the focusing effect achieved by the ODCM is similar to that of a traditional circular metalens.

A highly sensitive strain sensor based on a silica@polyaniline core-shell particle reinforced hydrogel with excellent flexibility, stretchability, toughness and conductivity.

Hydrogel-based flexible strain sensors for personal health monitoring and human-machine interaction have attracted wide interest among researchers. In this paper, hydrophobic association and nanocomposite conductive hydrogels were successfully prepared by introducing polyaniline coated silica (SiO2@PANI) core-shell particles into an acrylamide-lauryl methacrylate (P(AM/LMA)) copolymer matrix. The hydrophobic interaction between the SiO2@PANI core-shell particles and the hydrophobic LMA in the P(AM/LMA) chains induced the hydrogels with outstanding mechanical properties. Furthermore, the polyaniline on the SiO2 surface and the inorganic salt formed a conductive network, which synergistically enhanced the conductivity of the hydrogels. The obtained hydrogels integrate high tensile strength (1398 kPa), ultra-stretchability (>1000%), wonderful strain sensitivity (gauge factor = 10.407 at 100-1100% strain), quick response (300 ms), and excellent durability (>300 cycles) due to the hydrophobic association and nanocomposite effect. The prepared SiO2@PANI-P(AM/LMA) hydrogel shows high stress sensitivity to detect human movements and displays a broad application prospect in flexible strain-sensor field.

Broadband and high-efficiency spin-polarized wave engineering with PB metasurfaces.

Manipulating circularly polarized (CP) light waves at will are highly important for photonic researches and applications. Recently, while Pancharatnam-Berry (PB) metasurfaces have shown unprecedented capabilities to control CP light, meta-devices constructed so far always suffer from the limitations of low-efficiency and narrow bandwidth. Here, we propose a scheme to construct PB metasurfaces with these two issues well addressed. To verify our idea, two PB meta-devices are designed and fabricated for achieving high-efficiency and broadband photonic spin Hall effect and focusing effect, respectively. Experimental results, in good agreement with full wave simulations, demonstrate the desired functionalities with efficiencies reaching 80% within an ultra-wide frequency band (8.2-17.3GHz). The proposed design scheme is generic and can be extended to high-frequency regimes. Our work can stimulate the realizations of high-performance and broadband PB meta-devices with diversified functionalities.

Black silicon Schottky photodetector in sub-bandgap near-infrared regime.

Sub-bandgap near-infrared silicon (Si) photodetectors are key elements in integrated Si photonics. We demonstrate such a Si photodetector based on a black Si (b-Si)/Ag nanoparticles (Ag-NPs) Schottky junction. This photodetector synergistically employs the mechanisms of inner photoemission, light-trapping, and surface-plasmon-enhanced absorption to efficiently absorb the sub-bandgap light and generate a photocurrent. The b-Si/Ag-NPs sample was prepared by means of wet chemical etching. Compared to those of a planar-Si/Ag thin-film Schottky photodetector, the responsivities of the b-Si/Ag-NPs photodetector were greatly enhanced, being 0.277 and 0.226 mA/W at a reversely biased voltage of 3 V for 1319- and 1550-nm light, respectively.

Hybridization-induced broadband terahertz wave absorption with graphene metasurfaces.

Electromagnetic (EM) wave absorption plays a vital role in photonics. While metasurfaces are proposed to absorb EM waves efficiently, most of them exhibit limited bandwidth and fixed functionalities. Here, we propose a broadband and tunable terahertz (THz) absorber based on a graphene-based metasurface, which is constructed by a single layer of closely patterned graphene concentric double rings and a metallic mirror separated by an ultrathin SiO2 layer. Plasmonic hybridization between two graphene rings significantly enlarges the absorption bandwidth, which can be further tuned by gating the graphene. Moreover, the specific design also makes our device insensitive to the incident angle and polarization state of impinging EM waves. Our results may inspire certain wave-modulation-related applications, such as THz imaging, smart absorber, tunable sensor, etc.

A synergetic application of surface plasmon and field effect to improve Si solar cell performance.

We report a synergetic application of surface plasmon (SP) and field effect (FE) to improve crystalline Si solar cell performance. The SPs are supported by small-sized Ag nanoparticles with an average diameter of 36.7 nm. The localized SP electromagnetic field from Ag nanoparticles excites extra electron-hole pairs at the surface region of the Si solar cell emitter, and meanwhile, the electron-hole pairs are detached by the electrostatic field that crosses the emitter surface. This synergism of SP and FE produces extra charges and enhances the Si solar cell efficiency. As compared to a Si solar cell applying SP and FE independently, a more than 10% efficiency enhancement is achieved by using them synergistically.

Experimental verifications on an effective model for photonic coupling.

Combining near-field measurements with coupled-mode-theory analyses, we unambiguously identify all resonant modes in coupled systems containing two photonic resonators. Based on this technique, we perform extensive microwave experiments to study how the inter-resonator coupling varies against various configurational parameters. Our experimental results quantitatively verify a previously established effective model for photonic coupling, and highlight the importance of quadrupole terms in certain situations.

Tailor the Functionalities of Metasurfaces Based on a Complete Phase Diagram.

Metasurfaces in a metal-insulator-metal configuration have been widely used in photonics, with applications ranging from perfect absorption to phase modulation, but why and when such structures can realize what functionalities are not yet fully understood. Here, we establish a complete phase diagram in which the optical properties of such systems are fully controlled by two simple parameters (i.e., the intrinsic and radiation losses), which are, in turn, dictated by the geometrical or material properties of the underlying structures. Such a phase diagram can greatly facilitate the design of appropriate metasurfaces with tailored functionalities demonstrated by our experiments and simulations in the terahertz regime. In particular, our experiments show that, through appropriate structural or material tuning, the device can be switched across the phase boundaries yielding dramatic changes in optical responses. Our discoveries lay a solid basis for realizing functional and tunable photonic devices with such structures.

High-efficiency broadband meta-hologram with polarization-controlled dual images.

Holograms, the optical devices to reconstruct predesigned images, show many applications in our daily life. However, applications of hologram are still limited by the constituent materials and therefore their working range is trapped at a particular electromagnetic region. In recent years, the metasurfaces, an array of subwavelength antenna with varying sizes, show the abilities to manipulate the phase of incident electromagnetic wave from visible to microwave frequencies. Here, we present a reflective-type and high-efficiency meta-hologram fabricated by metasurface for visible wavelength. Using gold cross nanoantennas as building blocks to construct our meta-hologram devices with thickness ∼ λ/4, the reconstructed images of meta-hologram show polarization-controlled dual images with high contrast, functioning for both coherent and incoherent light sources within a broad spectral range and under a wide range of incidence angles. The flexibility demonstrated here for our meta-hologram paves the road to a wide range of applications related to holographic images at arbitrary electromagnetic wave region.

Nondestructive estimation method of live chicken leg weight based on deep learning.

In the broiler-breeding industry, phenotype determination is critical. Leg weight is a fundamental indicator for breeding, and noninvasive testing technology can reduce damage to animals. This study proposes a broiler leg weight estimation system comprising a weight-estimation model and computed tomography (CT) acquisition equipment. The weight-estimation model can automatically process the scan results of live broiler chickens from the CT acquisition equipment. The weight-estimation model comprises an improved you-only-look-once (YOLOv5) segmentation algorithm and a random forest fitting network. The segmentation head was introduced into the YOLOv5 network, combined with a multiscale attention mechanism and an atrous spatial pyramid pooling architecture, and a new network model, YOLO- measuring chicken leg weight (YOLO-MCLW), was proposed to improve segmentation efficiency and accuracy. Morphological parameters were extracted from the obtained mask image, and a random forest network was used for fitting. The experiments show that the system exhibited an average absolute error of 7.27 g and an average percentage error of 4.82% in tests on 50 individual legs of 25 broiler chickens. The prediction R2 of broiler chicken legs can reaches 88.98%, the segmentation intersection over union result reaches 95.45%, and 37.04 images are processed per second. This system provides technical support for the part determination of broiler chickens in commercial breeding.