Bioinspired Surface Functionalization of Poly(ether ether ketone) for Enhancing Osteogenesis and Bacterial Resistance.

In orthopedics, developing functionalized biomaterials to enhance osteogenesis and bacterial resistance is crucial. Although poly(ether ether ketone) (PEEK) is regarded as an important engineering plastic for biomedical material with excellent mechanical properties and biocompatibility, its biological inertness has greatly compromised its application in biomedical engineering. Inspired by the catecholamine chemistry of mussels, we propose a universal and versatile approach for enhancing the osteogenesis and antibacterial performances of PEEK based on surface functionalization of polydopamine-modified nanohydroxyapatite and lysozyme simultaneously. The characterizations of surface morphology and elemental composition revealed that the composite coating was successfully added to the PEEK surface. Additionally, the in vitro cell experiment and biomineralization assay indicated that the composite coating-modified PEEK was biocompatible with significantly improved bioactivity to promote osteogenesis and biomineralization compared with the untreated PEEK. Furthermore, the antibacterial test demonstrated that the composite coating had a strongly destructive effect on two bacteria (Staphylococcus aureus and Escherichia coli) with antibacterial ratios of 98.7% and 96.1%, respectively. In summary, the bioinspired method for surface functionalization can enhance the osteogenesis and bacterial resistance of biomedical materials, which may represent a potential approach for designing functionalized implants in orthopedics.

Study on synergistic inhibition and mechanism of flotation separation of fluorite and calcite by tannin and sodium humate.

At present, the separation technology of fluorite and calcite is still immature, and the research in this paper can promote the improvement of the separation technology of fluorite and calcite. The selective inhibition mechanism of tannin and humate sodium on calcite was studied by means of actual ore flotation test, single mineral flotation test, Zeta potential measurement and FT-IR spectroscopy. The results show that the mixture of tannin and sodium humate inhibitor has a good inhibitory effect on carbonate under weak alkaline condition. The reaction products of sodium humate, tannin and calcium ions in solution interact with organic compounds adsorbed on the surface of calcite, forming multilayer adsorption on the surface of calcite, making calcite more hydrophilic. Based on density functional theory, Materials Studio (MS) was used to calculate the relevant adsorption energy, and the result was as follows: (a) compared with fluorite, tannin and humate sodium molecules are more easily adsorbed on the surface of calcite. (b) Compared with calcite alone adsorption of tannin molecules or sodium humate molecules, the adsorption state will be more stable, and the effect of tannin and sodium humate synergistic inhibition of calcite is better than the effect of inhibition alone. Therefore, using tannin and sodium humate as a combination inhibitor can effectively separate fluorite and calcite, which will promote the development and utilization of fluorite ore in industry.

Research progress of TiO2-based photocatalytic degradation of wastewater: bibliometric analysis.

The pollution caused by modernization and industrialization has caused serious harm to the biodiversity of the earth. TiO2-based photocatalyst has been widely studied as an effective and sustainable water environment remediation material. In this study, we analyzed the status and research trends of TiO2-based photocatalytic degradation of wastewater in depression from 2003 to 2023 to provide a reference for further research. "Doping", "Modification" and "Heterojunction" were used as keywords, and 817 related academic literatures were screened out by using Web of Science database. Through the visualization software VOSviewer and CiteSpace, the authors, institutions and literature keywords were clustered. The results show that since 2008, the annual number of published papers on TiO2-based photocatalytic degradation of wastewater has increased from 9 to 114. Among them, China has published 432 articles and made great contributions, and there are many representative research teams. Chinese universities are the main body to study TiO2-based photocatalytic degradation of wastewater, but the cooperation between universities is not as close as that abroad. This paper comprehensively analyzes the research hotspots of TiO2-based photocatalytic degradation of wastewater, such as the doping of TiO2 and the construction of different types of heterojunctions of TiO2. It is expected that these analysis results will provide new research ideas for researchers to carry out future research on related topics and let researchers know in-depth research institutions and possible collaborators to conduct academic exchanges and discussions with active institutions.

Photocatalytic degradation of reactive brilliant blue KN-R by Ti-doped Bi2O3.

In this study, different compositions of Ti-doped Bi2O3 photocatalytic materials were prepared by chemical solution decomposition method. It was used to degrade reactive brilliant blue KN-R, and then characterized by XRD, SEM, UV-vis DRS, XPS, photocurrent, and other detection methods. The results show that when the catalyst dosage is 1.0 g/L and the initial concentration of reactive brilliant blue KN-R is 20 mg/L, the degradation rate of pure Bi2O3 to reactive brilliant blue KN-R is 75.30%; the Ti doping amount is 4% (4Ti/Bi2O3), 4Ti/Bi2O3 had the best degradation effect on reactive brilliant blue KN-R, and the degradation rate could reach 93.27%. When 4Ti/Bi2O3 was reused for 4 times, the degradation rate of reactive brilliant blue KN-R only decreased by 6.91%. Doping Ti can inhibit the growth of Bi2O3 grains, making the XRD peak of Ti/Bi2O3 material wider. The pure Bi2O3 particles are larger and the surface is smooth. With the increase of Ti doping content, the surface of Ti/Bi2O3 material grows from roughness to nanofibrous Bi4Ti3O12. The visible light absorption performance and electron separation and transfer ability of Bi2O3 are significantly improved by doping Ti ions. The band gap is reduced from 2.81 to 2.75 eV. In conclusion, doping Ti enhances the visible light absorption and electron separation and transfer capabilities of Bi2O3, reduces the band gap, and improves the surface morphology, which makes Bi2O3 have higher photocatalytic performance.